B(C F ) 催化的烯烃的 E-选择性异构化。
B(C F ) -Catalyzed E-Selective Isomerization of Alkenes.
机构信息
Cardiff Catalysis Institute, School of Chemistry, Cardiff University Main Building, Park Place, Cardiff, CF10 3AT, UK.
Department of Chemistry, University of Bath, Bath, BA2 7AY, UK.
出版信息
Chemistry. 2022 Nov 11;28(63):e202202454. doi: 10.1002/chem.202202454. Epub 2022 Sep 1.
Herein, we report the B(C F ) -catalyzed E-selective isomerization of alkenes. The transition-metal-free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.
在此，我们报告了 B(C F ) 催化的烯烃 E-选择性异构化。该无过渡金属方法适用于各种易得的底物，可获得广泛的含有多功能立体定义的内部烯烃的合成有用的产物。通过使用合成和计算方法研究了反应机理。
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