Giza Krystyna, Owczarek Edyta
Faculty of Production Engineering and Materials Technology, Czestochowa University of Technology, Av. Armii Krajowej 19, 42-218 Częstochowa, Poland.
Micromachines (Basel). 2022 Jul 28;13(8):1192. doi: 10.3390/mi13081192.
This study analysed the corrosion parameters of LaNiMg hydrogen-absorbing alloys depending on the degree of replacement of nickel with magnesium and the exposure time of samples in a strongly alkaline solution. The microstructure and composition of the alloys were analysed using SEM and EDS, respectively. A correlation was observed between the corrosion rate and the magnesium content in the alloy and the exposure time of the investigated materials in the corrosive solution. The obtained research results showed that the LaNi phase, rich in Mg, corroded easily, and the presence of Mg in LaNiMg alloys became beneficial only for longer exposure times of samples in an alkaline solution. The corrosion layer formed during the contact of the magnesium alloys with the electrolyte promoted faster H evolution compared to the non-magnesium-substituted alloy.
本研究分析了LaNiMg储氢合金的腐蚀参数,该参数取决于镁替代镍的程度以及样品在强碱性溶液中的暴露时间。分别使用扫描电子显微镜(SEM)和能谱仪(EDS)对合金的微观结构和成分进行了分析。观察到腐蚀速率与合金中的镁含量以及被研究材料在腐蚀溶液中的暴露时间之间存在相关性。获得的研究结果表明,富含镁的LaNi相容易腐蚀,并且LaNiMg合金中镁的存在仅在样品在碱性溶液中暴露较长时间时才有益。与未用镁替代的合金相比,镁合金与电解质接触时形成的腐蚀层促进了更快的氢析出。