Doyle Lucia, Weidlich Ingo, Di Maio Ernesto
Technical Infrastructure Management, HafenCity University, 20457 Hamburg, Germany.
Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, University of Naples Federico II, 80138 Naples, Italy.
Materials (Basel). 2022 Sep 7;15(18):6212. doi: 10.3390/ma15186212.
Insulating polymeric foams have an important role to play in increasing energy efficiency and therefore contributing to combating climate change. Their development in recent years has been driven towards the reduction of thermal conductivity and achievement of the required mechanical properties as main targets towards sustainability. This perception of sustainability has overseen the choice of raw materials, which are often toxic, or has placed research efforts on optimizing one constituent while the other necessary reactants remain hazardous. The transition to the circular economy requires a holistic understanding of sustainability and a shift in design methodology and the resulting research focus. This paper identifies research needs and possible strategies for polymeric foam development compatible with Circular Product Design and Green Engineering, based on an extensive literature review. Identified research needs include material characterization of a broader spectrum of polymer melt-gas solutions, ageing behavior, tailoring of the polymer chains, detailed understanding and modeling of the effects of shear on cell nucleation, and the upscaling of processing tools allowing for high and defined pressure drop rates.
绝缘聚合物泡沫在提高能源效率从而助力应对气候变化方面发挥着重要作用。近年来,它们的发展以降低热导率和实现所需机械性能为主要目标,朝着可持续性方向推进。这种对可持续性的认知主导了原材料的选择,而这些原材料往往有毒,或者在优化一种成分的同时,其他必要反应物仍具有危险性。向循环经济的转变需要对可持续性有全面的理解,并转变设计方法以及随之而来的研究重点。本文在广泛的文献综述基础上,确定了与循环产品设计和绿色工程兼容的聚合物泡沫开发的研究需求和可能策略。确定的研究需求包括对更广泛的聚合物熔体 - 气体溶液进行材料表征、老化行为、聚合物链的定制、对剪切对泡孔成核影响的详细理解和建模,以及扩大加工工具规模以实现高且确定的压降速率。