A review of the application of cerium and lanthanum in phosphorus removal during wastewater treatment: Characteristics, mechanism, and recovery.

Owing to their strong bond with anions, rare earth elements (REEs) are prime contenders in wastewater treatment to meet the stringent phosphorus (P) effluent quality requirements. REEs outcompete traditional metals to abate phosphorus. The application of lanthanides in wastewater treatment is mainly through adsorption, where REEs are incorporated into a carrier matrix to improve the adsorption capacity. As coagulants, information on the performance of lanthanides is lacking. In this review, the performance of major water coagulants (iron and aluminum) is discussed and compared to two lanthanides: cerium and lanthanum. The use of lanthanides as adsorbents and as coagulants is elucidated during P treatment. The recovery of P and REEs is also discussed. Where details were lacking in the literature, experiments were conducted to fill these research gaps. Using REEs as adsorbents limits their P precipitation potential; as coagulants, REE capacity is 520.79 mg P/g La and 469.96 mg P/g Ce. In addition, as coagulants, they are not affected by pH (3.0 < pH < 10.0); however, carbonates and sulfate are the major species that can reduce the performance of REEs during P treatment. REE-P precipitation is orchestrated through the formation of an REE-PO bond. Unfortunately, this strong bond between lanthanides and phosphate makes phosphate recovery almost impractical. If the goal is to recover REEs and reuse P in other applications like fertilizers, REEs are not the best candidates. We recommend additional research dedicated to understanding lanthanide coagulants in typical wastewater treatment facilities and their release from phosphate precipitates under different environmental conditions.