Center for Nano Science and Technology@PoliMi, Istituto Italiano di Tecnologia, via Giovanni Pascoli 70/3, Milano 20133, Italy.
ACS Sens. 2022 Oct 28;7(10):2995-3005. doi: 10.1021/acssensors.2c01280. Epub 2022 Oct 12.
Improper freezing of food causes food waste and negatively impacts the environment. In this work, we propose a device that can detect defrosting events by coupling a temperature-activated galvanic cell with an ionochromic cell, which is activated by the release of ions during current flow. Both the components of the sensor are fabricated through simple and low-energy-consuming procedures from edible materials. The galvanic cell operates with an aqueous electrolyte solution, producing current only at temperatures above the freezing point of the solution. The ionochromic cell exploits the current generated during the defrosting to release tin ions, which form complexes with natural dyes, causing the color change. Therefore, this sensor provides information about defrosting events. The temperature at which the sensor reacts can be tuned between 0 and -50 °C. The device can thus be flexibly used in the supply chain: as a sensor, it can measure the length of exposure to above-the-threshold temperatures, while as a detector, it can provide a signal that there was exposure to above-the-threshold temperatures. Such a device can ensure that frozen food is handled correctly and is safe for consumption. As a sensor, it could be used by the workers in the supply chain, while as a detector, it could be useful for end consumers, ensuring that the food was properly frozen during the whole supply chain.
食物的不当冻结会导致食物浪费,并对环境产生负面影响。在这项工作中,我们提出了一种通过将温度激活的原电池与离子变色电池耦合来检测解冻事件的装置,该电池通过电流流动过程中释放的离子而被激活。传感器的两个组件都是通过简单且低能耗的程序,由食用材料制成的。原电池使用水基电解质溶液工作,仅在高于溶液冰点的温度下产生电流。离子变色电池利用解冻过程中产生的电流释放锡离子,这些离子与天然染料形成配合物,导致颜色变化。因此,该传感器提供了有关解冻事件的信息。传感器反应的温度可以在 0 到-50°C 之间进行调节。因此,该设备可以灵活地应用于供应链中:作为传感器,可以测量暴露在高于阈值温度的时间长度,而作为探测器,可以发出信号表明曾暴露在高于阈值的温度下。这样的设备可以确保冷冻食品得到正确处理,并且可以安全食用。作为传感器,它可以供供应链中的工人使用,而作为探测器,它可以供最终消费者使用,确保食品在整个供应链中都被正确冷冻。