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一种预测有机微污染物在活性炭上吸附情况的快速测试方法。

A quick test method for predicting the adsorption of organic micropollutants on activated carbon.

作者信息

Zhang Qiqi, Jekel Martin, Zhang Yongjun, Ruhl Aki Sebastian

机构信息

School of Environmental Science and Engineering, Nanjing Tech University, Nanjing, PR China.

Technische Universität Berlin, Water Quality Control, Straße des 17. Juni 135, 10623 Berlin, Germany.

出版信息

Water Res. 2022 Nov 1;226:119217. doi: 10.1016/j.watres.2022.119217. Epub 2022 Oct 7.

Abstract

Controlling the contamination of water cycles with organic micropollutants (OMPs) has been targeted in many regions. Adsorption with activated carbon is an effective technology to remove OMPs from different water matrices. To efficiently design or operate the adsorption process, the adsorption of OMPs should be properly assessed, usually with time-consuming batch adsorption tests and sophisticated analyses. In this study, a quick adsorption test method has been developed by loading powdered activated carbon (PAC) into a syringe filter which can be used subsequently to filtrate the water sample in short time (<60 s). Treated wastewater was applied to compare the quick test method and conventional batch test regarding the adsorption of 14 frequently detected OMPs, the abatement of UV, and changes in fractions of dissolved organic matter (DOM). Similar adsorption patterns of individual OMPs, total OMPs, and DOM fractions was found with two methods. UV can predict the removal of total OMPs and most individual OMPs in both methods. Both the abatement of UV or the removal of OMPs determined in the quick test led to a highly accurate prediction of OMP adsorption in the conventional adsorption tests. The novel quick test method thus could help operators and researchers quickly monitor the adsorption capacity of PAC products.

摘要

许多地区都将控制有机微污染物(OMPs)对水循环的污染作为目标。用活性炭吸附是从不同水体基质中去除OMPs的有效技术。为了有效地设计或运行吸附过程,通常需要通过耗时的批量吸附试验和复杂的分析来正确评估OMPs的吸附情况。在本研究中,开发了一种快速吸附测试方法,即将粉末状活性炭(PAC)装入注射器过滤器中,随后可用于在短时间内(<60秒)过滤水样。应用处理后的废水,比较快速测试方法和传统批量测试在14种常见检测到的OMPs吸附、紫外线去除以及溶解有机物(DOM)组分变化方面的情况。两种方法发现单个OMPs、总OMPs和DOM组分具有相似的吸附模式。紫外线可以预测两种方法中总OMPs和大多数单个OMPs的去除情况。快速测试中测定的紫外线去除或OMPs去除都能高度准确地预测传统吸附试验中OMPs的吸附情况。因此,这种新型快速测试方法可以帮助操作人员和研究人员快速监测PAC产品的吸附能力。

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