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采用 GC-MS、GC-O、嗅闻阈值和感官分析评估白酒中酯类香气物质与非挥发性有机酸的感知相互作用。

Evaluation of the Perceptual Interaction among Ester Odorants and Nonvolatile Organic Acids in Baijiu by GC-MS, GC-O, Odor Threshold, and Sensory Analysis.

机构信息

Beijing Laboratory of Food Quality and Safety, Beijing Technology and Business University, Beijing 100048, China.

Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing 100048, China.

出版信息

J Agric Food Chem. 2022 Nov 2;70(43):13987-13995. doi: 10.1021/acs.jafc.2c04321. Epub 2022 Oct 21.

Abstract

By applying the aroma extract dilution analysis, 13 esters were found to have high FD factors in the flavor type of Baijiu. These were then quantified using GC-MS. In addition, 35 nonvolatile organic acids were quantified by a derivatization method combined with GC-MS. The perceptual interactions of lactic acid and ethyl lactate and that of lactic acid and ethyl acetate were studied through the olfactory threshold. The S curve was used to evaluate the changes in the olfactory thresholds. After adding lactic acid (1142, 20 000, and 53 703 mg/L), the olfactory thresholds of ethyl lactate (1000, 724, and 295 mg/L) and ethyl acetate (398, 324, and 257 mg/L) decreased obviously, which revealed that lactic acid gave additive or synergistic odor effects for the two esters. Furthermore, it was discovered that as the concentrations of lactic acid increased, the extent of the interaction among these compounds was also greater in the mixture.

摘要

通过应用香气提取稀释分析,在白酒风味类型中发现 13 种酯具有较高的 FD 因子。然后使用 GC-MS 对其进行定量。此外,还通过衍生化结合 GC-MS 定量了 35 种非挥发性有机酸。通过嗅觉阈值研究了乳酸和乳酸乙酯以及乳酸和乙酸乙酯的感官相互作用。使用 S 曲线评估了嗅觉阈值的变化。添加乳酸(1142、20000 和 53703 mg/L)后,乳酸乙酯(1000、724 和 295 mg/L)和乙酸乙酯(398、324 和 257 mg/L)的嗅觉阈值明显降低,表明乳酸对这两种酯具有加性或协同的气味效应。此外,还发现随着乳酸浓度的增加,混合物中这些化合物之间的相互作用程度也更大。

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