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10 - [(4 - 硝基 - 苯基)乙炔基] - 10 - 吩噻嗪

10-[(4-Nitro-phen-yl)ethyn-yl]-10-pheno-thia-zine.

作者信息

Okuno Tsunehisa, Doi Ikue

机构信息

Department of Systems Engineering, Wakayama University, Sakaedani, Wakayama, 640-8510, Japan.

出版信息

IUCrdata. 2022 Oct 27;7(Pt 9):x220942. doi: 10.1107/S2414314622009427. eCollection 2022 Sep.

DOI:10.1107/S2414314622009427
PMID:36337462
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9635434/
Abstract

The title compound, CHNOS, is a 10-ethynyl-10-pheno-thia-zine derivative. The pheno-thia-zine unit has a butterfly shape, where the folding angle between the two benzene rings is 153.87 (7)°, which is almost as in other reported pheno-thia-zine derivatives. The dihedral angle between the mean plane including the C atoms bonded to the pheno-thia-zine N atom and the benzene ring of the nitro-benzene group is 10.34 (5)°. The near planar geometry of the mol-ecule is reasonably explained by intra-molecular charge-transfer inter-actions.

摘要

标题化合物CHNOS是一种10-乙炔基-10-吩噻嗪衍生物。吩噻嗪单元呈蝴蝶形状，两个苯环之间的折叠角为153.87 (7)°，这与其他报道的吩噻嗪衍生物几乎相同。包含与吩噻嗪N原子相连的C原子的平均平面与硝基苯基团的苯环之间的二面角为10.34 (5)°。分子的近似平面几何形状可通过分子内电荷转移相互作用得到合理的解释。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4bd5/9635434/d390d784f6b2/x-07-x220942-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4bd5/9635434/d390d784f6b2/x-07-x220942-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4bd5/9635434/d390d784f6b2/x-07-x220942-fig1.jpg

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本文引用的文献

1
Transannular S···N interactions in 10-ethynyl-10H-phenothiazine 5-oxide and 5,5-dioxide.10-乙炔基-10H-吩噻嗪5-氧化物和5,5-二氧化物中的跨环S···N相互作用
Acta Crystallogr C. 2013 Dec 15;69(Pt 12):1553-6. doi: 10.1107/S0108270113031661. Epub 2013 Nov 30.
2
10-(Prop-1-yn-1-yl)-10H-phenothia-zine.10 -（丙 - 1 - 炔 - 1 - 基）- 10H - 吩噻嗪
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2790. doi: 10.1107/S1600536812036537. Epub 2012 Aug 25.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
Remarkable structure deformation in phenothiazine trimer radical cation.吩噻嗪三聚体自由基阳离子中显著的结构变形。
Org Lett. 2004 Sep 30;6(20):3493-6. doi: 10.1021/ol048698z.
5
Donor-acceptor (electronic) coupling in the precursor complex to organic electron transfer: intermolecular and intramolecular self-exchange between phenothiazine redox centers.有机电子转移前体复合物中的给体-受体（电子）耦合：吩噻嗪氧化还原中心之间的分子间和分子内自交换。
J Am Chem Soc. 2004 Feb 11;126(5):1388-401. doi: 10.1021/ja038746v.