Okuno Tsunehisa, Doi Ikue
Department of Systems Engineering, Wakayama University, Sakaedani, Wakayama, 640-8510, Japan.
IUCrdata. 2022 Oct 27;7(Pt 9):x220942. doi: 10.1107/S2414314622009427. eCollection 2022 Sep.
The title compound, CHNOS, is a 10-ethynyl-10-pheno-thia-zine derivative. The pheno-thia-zine unit has a butterfly shape, where the folding angle between the two benzene rings is 153.87 (7)°, which is almost as in other reported pheno-thia-zine derivatives. The dihedral angle between the mean plane including the C atoms bonded to the pheno-thia-zine N atom and the benzene ring of the nitro-benzene group is 10.34 (5)°. The near planar geometry of the mol-ecule is reasonably explained by intra-molecular charge-transfer inter-actions.
标题化合物CHNOS是一种10-乙炔基-10-吩噻嗪衍生物。吩噻嗪单元呈蝴蝶形状,两个苯环之间的折叠角为153.87 (7)°,这与其他报道的吩噻嗪衍生物几乎相同。包含与吩噻嗪N原子相连的C原子的平均平面与硝基苯基团的苯环之间的二面角为10.34 (5)°。分子的近似平面几何形状可通过分子内电荷转移相互作用得到合理的解释。