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T9和SPCC钢表面渗铬层的制备、缓蚀及耐磨性能研究

Investigation of the Preparation, Corrosion Inhibition, and Wear Resistance of the Chromized Layer on the Surfaces of T9 and SPCC Steels.

作者信息

Liu Sainan, Yang Jing, Liang Xiao, Sun Yangyang, Zhao Xiaojun, Cai Zhenyang

机构信息

School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China.

School of Materials Science and Engineering, Central South University, Changsha 410083, China.

出版信息

Materials (Basel). 2022 Nov 9;15(22):7902. doi: 10.3390/ma15227902.

Abstract

To improve the corrosion inhibition and wear resistance of materials, the pack cementation method was used to prepare chromized coatings on the surfaces of high-carbon T9 steel and low-carbon SPCC steel. The results showed the formation of a uniform and dense double-layer structure with a thickness of ~10 μm on the surfaces of two different types of steel. The coating layer for T9 steel was mainly composed of CrC and CrC, while that for SPCC steel was mainly composed of CrC and Fe-Cr solid solution. Additionally, both of the steels showed different hardness distributions. The hardness measurements of the outer layers of the T9 steel and SPCC steel were ~1737.72 HV and 1771.91 HV, while the hardness values of the secondary layers were 1378.31 HV and 448.52 HV, respectively. The polarization curves in 3.5 wt.% NaCl solution demonstrated the better corrosion resistance of the chromized coating. Chromizing increased the corrosion potential by ~0.2 V and reduced the corrosion current density by one order of magnitude. Under the presence of an 8 N load, the friction factor before and after the chromizing of T9 steel was about 0.69, and the mass wears were 2 mg and 0.6 mg, respectively. Meanwhile, the friction factor of the SPCC steel before and after chromizing was about 0.73, with respective mass wears of 2 mg and 2.9 mg. The wear resistance of T9 steel after chromizing was superior, but it became worse after chromizing for the SPCC steel.

摘要

为提高材料的耐腐蚀性和耐磨性,采用包埋渗金属法在高碳T9钢和低碳SPCC钢表面制备渗铬涂层。结果表明,在两种不同类型的钢表面形成了厚度约为10μm的均匀致密双层结构。T9钢的涂层主要由CrC和CrC组成,而SPCC钢的涂层主要由CrC和Fe-Cr固溶体组成。此外,两种钢都表现出不同的硬度分布。T9钢和SPCC钢外层的硬度测量值分别约为1737.72 HV和1771.91 HV,而次层的硬度值分别为1378.31 HV和448.52 HV。在3.5 wt.% NaCl溶液中的极化曲线表明渗铬涂层具有更好的耐腐蚀性。渗铬使腐蚀电位提高了约0.2 V,腐蚀电流密度降低了一个数量级。在8 N载荷作用下,T9钢渗铬前后的摩擦系数约为0.69,质量磨损分别为2 mg和0.6 mg。同时,SPCC钢渗铬前后的摩擦系数约为0.73,质量磨损分别为2 mg和2.9 mg。T9钢渗铬后的耐磨性较好,但SPCC钢渗铬后的耐磨性变差。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d948/9699551/b3bb120e01c1/materials-15-07902-g001.jpg

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