Jia Qianqian, Chen Jiachuan, Yang Guihua, Liu Kefeng, Wang Yueying, Zhang Kai
State Key Laboratory of Biobased Materials and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China.
Polymers (Basel). 2022 Nov 25;14(23):5129. doi: 10.3390/polym14235129.
Based on the reduction of environmental pollution, a biological enzyme assisted alkali-oxygen pulping method was explored to improve the delignification efficiency and fiber accessibility of wheat straw and improve the properties of wheat straw pulp. In this paper, lipase and xylanase were used to pretreat wheat straw and the effects of different enzyme types and enzyme dosage on the microstructure and pulp properties of wheat straw were investigated and experimented. The results showed that the lipase can remove fat and wax on the surface of wheat straw, while xylanase degraded the hemicellulose components, such as xylan, of wheat straw fiber, destroyed the structure of the lignin-carbohydrate complex, increasing lignin removal as a result and enhancing the impregnating, diffusion and penetration of alkali. Compared with wheat straw without enzyme pretreatment, the skeleton of wheat straw pretreated by enzyme became looser, the internal cavity appeared and the wall cavity became thin and transparent. The fines decreased obviously and the length of fibers increased. After combined pretreatment with lipase (15 U·g) and xylanase (15 U·g), the pulping performance of wheat straw was improved and the tensile index (97.37 N·m·g), brightness (40.9% ISO) and yield (58.10%) of the pulp increased by 12.9%, 19.9% and 9.9%, respectively. It can be seen that enzyme pretreatment is a green and effective approach to improving the alkali-oxygen pulping performance of wheat straw.
基于减少环境污染的目的,探索了一种生物酶辅助碱-氧制浆方法,以提高麦草的脱木素效率和纤维可及性,并改善麦草浆的性能。本文采用脂肪酶和木聚糖酶对麦草进行预处理,研究并试验了不同酶种类和酶用量对麦草微观结构和纸浆性能的影响。结果表明,脂肪酶可去除麦草表面的油脂和蜡质,而木聚糖酶可降解麦草纤维中的半纤维素成分(如木聚糖),破坏木素-碳水化合物复合体的结构,从而增加木素的脱除量,并增强碱液的浸渍、扩散和渗透能力。与未经酶预处理的麦草相比,经酶预处理的麦草骨架变得更疏松,内部出现腔隙,壁腔变薄且透明。细小纤维明显减少,纤维长度增加。经脂肪酶(15 U·g)和木聚糖酶(15 U·g)联合预处理后,麦草的制浆性能得到改善,纸浆的抗张指数(97.37 N·m·g)、亮度(40.9% ISO)和得率(58.10%)分别提高了12.9%、19.9%和9.9%。可见,酶预处理是提高麦草碱-氧制浆性能的一种绿色有效方法。