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来自消费后塑料包装废弃物的混合聚乙烯组分的机械性能和热性能

Mechanical and Thermal Properties of Mixed PE Fractions from Post-Consumer Plastic Packaging Waste.

作者信息

Boz Noyan Ezgi C, Venkatesh Abhijit, Boldizar Antal

机构信息

Department of Industrial and Materials Science, Chalmers University of Technology, Gothenburg 41296, Sweden.

出版信息

ACS Omega. 2022 Dec 1;7(49):45181-45188. doi: 10.1021/acsomega.2c05621. eCollection 2022 Dec 13.

Abstract

The functional properties of recycled post-consumer flexible polyethylene packaging waste have been studied using materials collected and sorted at a large-scale facility in Sweden. The studied fraction was used both as received and after simple laboratory washing in water with added sodium hydroxide at 40 °C. The materials were melt-compounded with a twin-screw extruder using two different temperature profiles and two screw configurations and injection-molded into slabs, whose thermal and mechanical properties were assessed. The results showed that the mechanical properties of injection-molded samples were not changed significantly either by the washing or by the temperature or screw configuration used in the compounding. Washing reduced the viscosity and molecular mass to a minor extent. As expected, the ash content of the compounded pellets was reduced by washing. The thermo-oxidative stability decreased with increasing compounding temperature and with washing.

摘要

利用在瑞典一家大型工厂收集和分类的材料,对回收的消费后柔性聚乙烯包装废弃物的功能特性进行了研究。所研究的部分材料既以原样使用,也在40°C下添加氢氧化钠的水中进行简单实验室洗涤后使用。使用双螺杆挤出机,采用两种不同的温度曲线和两种螺杆配置对材料进行熔融共混,然后注塑成板材,并对其热性能和机械性能进行评估。结果表明,注塑样品的机械性能不会因洗涤、共混时使用的温度或螺杆配置而发生显著变化。洗涤在一定程度上降低了粘度和分子量。正如预期的那样,洗涤降低了共混粒料的灰分含量。热氧化稳定性随着共混温度的升高和洗涤而降低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82e3/9753520/ecfb2987b996/ao2c05621_0002.jpg

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