Boz Noyan Ezgi C, Venkatesh Abhijit, Boldizar Antal
Department of Industrial and Materials Science, Chalmers University of Technology, Gothenburg 41296, Sweden.
ACS Omega. 2022 Dec 1;7(49):45181-45188. doi: 10.1021/acsomega.2c05621. eCollection 2022 Dec 13.
The functional properties of recycled post-consumer flexible polyethylene packaging waste have been studied using materials collected and sorted at a large-scale facility in Sweden. The studied fraction was used both as received and after simple laboratory washing in water with added sodium hydroxide at 40 °C. The materials were melt-compounded with a twin-screw extruder using two different temperature profiles and two screw configurations and injection-molded into slabs, whose thermal and mechanical properties were assessed. The results showed that the mechanical properties of injection-molded samples were not changed significantly either by the washing or by the temperature or screw configuration used in the compounding. Washing reduced the viscosity and molecular mass to a minor extent. As expected, the ash content of the compounded pellets was reduced by washing. The thermo-oxidative stability decreased with increasing compounding temperature and with washing.
利用在瑞典一家大型工厂收集和分类的材料,对回收的消费后柔性聚乙烯包装废弃物的功能特性进行了研究。所研究的部分材料既以原样使用,也在40°C下添加氢氧化钠的水中进行简单实验室洗涤后使用。使用双螺杆挤出机,采用两种不同的温度曲线和两种螺杆配置对材料进行熔融共混,然后注塑成板材,并对其热性能和机械性能进行评估。结果表明,注塑样品的机械性能不会因洗涤、共混时使用的温度或螺杆配置而发生显著变化。洗涤在一定程度上降低了粘度和分子量。正如预期的那样,洗涤降低了共混粒料的灰分含量。热氧化稳定性随着共混温度的升高和洗涤而降低。