Zhang Ce, Sun Ying, Xu Jing, Shi Xiaoping, Zhang Guoli
School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China.
Ministry of Education Key Laboratory of Advanced Textile Composite Materials, Institute of Composite Materials, Tiangong University, Tianjin 300387, China.
Polymers (Basel). 2022 Dec 19;14(24):5564. doi: 10.3390/polym14245564.
A composite thin shell with a high fiber volume fraction prepared by resin transfer molding (RTM) may have void defects, which create deformations in the final curing and lead to the final product being unable to meet the actual assembly requirements. Taking a helmet shell as an example, a multi-directional compression RTM (M-CRTM) method with an adjustable injection gap is proposed according to the shape of the thin shell. This method can increase the injection gap to reduce the fiber volume fraction during the injection process, making it easier for the resin to penetrate the reinforcement and for air bubbles to exit the mold. X-ray CT detection shows that the porosity of the helmet shell prepared by the newly developed technology is 36.6% lower than that of the RTM-molded sample. The void's distribution is more uniform, and its size is decreased, as is the number of voids, especially large voids. The results show that the maximum curing deformation of the M-CRTM-molded helmet shell is reduced by 13.7% compared to the RTM molded sample. This paper then further studies the deformation types of the shell and analyzes the causes of such results, which plays an important role in promoting the application of composite thin shells.
通过树脂传递模塑(RTM)制备的具有高纤维体积分数的复合薄壳可能存在孔隙缺陷,这些缺陷会在最终固化过程中产生变形,导致最终产品无法满足实际装配要求。以头盔壳为例,根据薄壳的形状提出了一种具有可调节注射间隙的多向压缩RTM(M-CRTM)方法。该方法可以在注射过程中增大注射间隙以降低纤维体积分数,使树脂更容易渗透增强材料并使气泡排出模具。X射线CT检测表明,采用新开发技术制备的头盔壳孔隙率比RTM模塑样品低36.6%。孔隙分布更均匀,尺寸减小,孔隙数量尤其是大孔隙数量减少。结果表明,与RTM模塑样品相比,M-CRTM模塑头盔壳的最大固化变形降低了13.7%。本文随后进一步研究了壳的变形类型并分析了产生此类结果的原因,这对促进复合薄壳的应用具有重要作用。