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结构色芳纶织物的构建及其作为可回收光子催化剂的应用。

Structurally colored aramid fabric construction and its application as a recyclable photonic catalyst.

机构信息

State Key Laboratory of New Textile Materials and Advanced Processing Technologies and Key Laboratory of Textile Fiber and Products of Ministry of Education, College of Materials Science and Engineering, Wuhan Textile University, Wuhan 430200, China.

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.

出版信息

Soft Matter. 2023 Jan 25;19(4):701-707. doi: 10.1039/d2sm01373h.

Abstract

Structural colors can be used in fabric coloring due to their bright color and non-fading properties. However, it is still a challenge to construct structural color on high crystallinity, smooth surfaced and yellow colored aramid fabrics. Herein, for the first time, photonic crystals (PCs) with structural color were constructed on aramid fabrics by introducing dopamine to modify aramid fabrics and synthesizing monodisperse high refractive index zinc sulfide nanoparticles (ZnS). The influence of the PC coatings on the structural color, mechanical properties, and thermal stability of the structurally colored aramid fabrics or fibers was further investigated. Moreover, due to the excellent catalytic properties of ZnS and the slow photon effects of PCs, the structurally colored fabrics showed good photocatalytic properties, which will be beneficial in reusing the catalysts, which is crucial to their application in the coloring of fabrics but also facilitates the recycling of waste PC coated aramid fabrics.

摘要

结构色由于其颜色鲜艳、不褪色的特性,可用于织物着色。然而,在高结晶度、表面光滑和黄色芳纶织物上构建结构色仍然是一个挑战。在此,首次通过引入多巴胺对芳纶织物进行改性并合成单分散高折射率硫化锌纳米粒子(ZnS),在芳纶织物上构建具有结构色的光子晶体(PCs)。进一步研究了 PC 涂层对结构色芳纶织物或纤维的结构色、力学性能和热稳定性的影响。此外,由于 ZnS 的优异催化性能和 PCs 的慢光子效应,结构色织物表现出良好的光催化性能,这将有利于催化剂的再利用,这对于其在织物着色中的应用至关重要,同时也有利于废弃 PC 涂层芳纶织物的回收。

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