Saadallah Yaakoub, Setifi Zouaoui, Geiger David K, Al-Douh Mohammed Hadi, Satour Achouak, Setifi Fatima
Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.
Département de Technologie, Faculté de Technologie, Université 20 Août 1955-Skikda, BP 26, Route d'El-Hadaiek, Skikda 21000, Algeria.
IUCrdata. 2022 Dec 23;7(Pt 12):x221180. doi: 10.1107/S2414314622011804. eCollection 2022 Dec.
The title compound, [Cu(CHNO)(CHN)], was synthesized solvothermally. The complex exhibits a distorted octa-hedral coordination geometry. The Cu atom is located on an inversion centre. The distorted octahedral CuN coordination sphere is composed of bidentate 2,2'-dipyrid-ylamine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra-cyano-2-eth-oxy-propenide ligands. In the crystal, N-H⋯N hydrogen bonding results in chains parallel to [010].
标题化合物[Cu(CHNO)(CHN)]通过溶剂热法合成。该配合物呈现出扭曲的八面体配位几何构型。铜原子位于对称中心上。扭曲的八面体CuN配位球在赤道位置由双齿的2,2'-联吡啶胺构成,而轴向位置则由1,1,3,3-四氰基-2-乙氧基丙烯配体占据。在晶体中,N-H⋯N氢键导致形成平行于[010]的链。