玻璃质无孔配位聚合物复合材料增强气体吸附选择性。
Composite with a Glassy Nonporous Coordination Polymer Enhances Gas Adsorption Selectivity.
机构信息
Graduate School of Environmental Science, Hokkaido University, Sapporo 060-0810, Japan.
Faculty of Environmental Earth Science, Hokkaido University, Sapporo 060-0810, Japan.
出版信息
Inorg Chem. 2023 Jan 23;62(3):1257-1263. doi: 10.1021/acs.inorgchem.2c04068. Epub 2023 Jan 12.
A glass-crystal composite (g-NCP/PCP), comprising a glassy nonporous coordination polymer (g-NCP) and a crystalline porous coordination polymer (PCP)/metal-organic framework, was synthesized by using a melt-quenched method. Compared to that of the PCP itself, g-NCP/PCP has an enhanced gas adsorption selectivity. The results should stimulate further studies of the chemistry of g-NCP/PCP glass-crystal composites.
采用熔融淬火法合成了一种玻璃-水晶复合材料（g-NCP/PCP），由无孔玻璃状配位聚合物（g-NCP）和结晶多孔配位聚合物（PCP）/金属有机骨架组成。与 PCP 本身相比，g-NCP/PCP 具有增强的气体吸附选择性。这一结果应激发对 g-NCP/PCP 玻璃-水晶复合材料化学的进一步研究。
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