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用于水电解槽的复合阴离子交换膜(AEMWE)的合成与表征

Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE).

作者信息

Rakhshani Somayyeh, Araneo Rodolfo, Pucci Andrea, Rinaldi Antonio, Giuliani Chiara, Pozio Alfonso

机构信息

Department of Astronautical, Electrical and Energy Engineering, University of Rome, Via Eudossiana 18, 00184 Rome, Italy.

Department of Chemistry and Industrial Chemistry, University of Pisa, Via Moruzzi 13, 56124 Pisa, Italy.

出版信息

Membranes (Basel). 2023 Jan 14;13(1):109. doi: 10.3390/membranes13010109.

Abstract

Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing AEM is an imperative step towards commercialization and plays a competitive role in the hydrogen production industry. In this article, we developed a composite anion exchange membrane prepared by activating a commercial support structure (Celgard 3401) with a commercially available functional group (Fumion FAA-3) through a phase-inversion process. Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis demonstrated the phase-inversion procedure as an effective methodology. Furthermore, the cell performance test result (with Celgard/Fumion) was very promising and even better in comparison with a commercial membrane commonly applied in alkaline electrolysis (Fumasep). We also developed a testing procedure for membrane performance evaluation during electrolysis which is very critical considering the effect of CO absorption on membrane conductivity.

摘要

阴离子交换膜(AEM)最近作为低成本水电解制氢系统的一个有前景的候选材料受到关注,该系统与可再生能源相连,是化石燃料的可持续替代方案。开发用于生产和分析AEM的潜在材料是迈向商业化的关键一步,并且在制氢行业中发挥着竞争作用。在本文中,我们通过相转化过程,用一种市售官能团(Fumion FAA-3)活化一种商业支撑结构(Celgard 3401),制备了一种复合阴离子交换膜。傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)分析表明相转化过程是一种有效的方法。此外,电池性能测试结果(Celgard/Fumion)非常有前景,与碱性电解中常用的商业膜(Fumasep)相比甚至更好。考虑到CO吸收对膜导电性的影响,我们还开发了一种电解过程中膜性能评估的测试程序,这一点非常关键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b96/9860756/e5a64c1ef31c/membranes-13-00109-g001.jpg

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