Liu Xinyou, Ma Wanrong, Tu Xinwei, Huang Houyi, Varodi Anca Maria
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China.
College of Furnishing and Industrial Design, Nanjing Forestry University, Str. Longpan No.159, Nanjing 210037, China.
Materials (Basel). 2023 Jan 29;16(3):1145. doi: 10.3390/ma16031145.
Luoyang No.1 is a Qing Dynasty (1644-1902) inland river ancient wooden shipwreck discovered in September 2013. It adds significantly to the study of Grand Canal transport history and Luoyang's economic history. The wood characteristics of Luoyang No.1 were investigated in this study using chemical compositions, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), nano-indentation (NI), and scanning electron microscopy (SEM). The results showed that the holocellulose content was only 32.84-37.69%, indicating that the cellulose and hemicellulose had been seriously degraded. Based on the XRD pattern, the degree of crystallinity of cellulose in wood ranged from 19.82 to 22.83%. The nano-indentation demonstrated that compared with the undegraded contemporary wood, the elastic modulus and hardness of the ancient ship wood decreased by 45.5% and 32.1%, respectively. Furthermore, the FTIR spectra revealed that the biological deterioration of ancient wood was indicated by a decrease in the peaks related to cellulose and hemicellulose, but the change in lignin was insignificant. The results could provide knowledge for appropriate dewatering, strengthening, restoration strategies and regulation of the museum environment.
“洛阳一号”是2013年9月发现的一艘清代(1644 - 1902年)内河古沉船。它对大运河运输史和洛阳经济史的研究具有重要意义。本研究采用化学成分分析、X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、纳米压痕(NI)和扫描电子显微镜(SEM)等方法对“洛阳一号”的木材特性进行了研究。结果表明,综纤维素含量仅为32.84 - 37.69%,表明纤维素和半纤维素已严重降解。根据XRD图谱,木材中纤维素的结晶度在19.82%至22.83%之间。纳米压痕测试表明,与未降解的当代木材相比,古船木的弹性模量和硬度分别下降了45.5%和32.1%。此外,FTIR光谱显示,古代木材的生物降解表现为与纤维素和半纤维素相关的峰减少,但木质素的变化不明显。这些结果可为古沉船的适当脱水、加固、修复策略及博物馆环境调控提供依据。