Revealing the Crystal Phase-Activity Relationship on NiRu Alloy Nanoparticles Encapsulated in N-Doped Carbon towards Efficient Hydrogen Evolution Reaction.

Adjusting the crystal phase of a metal alloy is an important method to optimize catalytic performance. However, detailed understanding about the phase-property relationship for the hydrogen evolution reaction (HER) is still limited. In this work, the crystal phase-activity relationship of NiRu nanoparticles is studied employing N-doped carbon shell coated NiRu nanoparticles with different phase contents. It is found that the NiRu@NC (mix) with both face-centred cubic (fcc) and thermodynamically unstable hexagonal close-packed (hcp) phase NiRu give the best HER performance. Further activity studies demonstrate that hcp NiRu has better HER performance, and NiRu@NC (mix) with rich (∼70 %) hcp phase presented outstanding performance with an overpotential of only 27 mV @ 10 mA ⋅ cm . The high HER activity of NiRu@NC (mix) is attributed to the formation of hcp phase. This finding indicates that the regulation of crystal structure can provide a new strategy for optimizing HER activity.