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用于可见光下降解罗丹明B的MoS纳米花修饰的CaTiO复合材料的光催化活性

Photocatalytic Activity of MoS Nanoflower-Modified CaTiO Composites for Degradation of RhB under Visible Light.

作者信息

Luo Minghan, Xu Jiaxing, Xu Wenjie, Zheng Yu, Wu Gongde, Jeong Taeseop

机构信息

School of Environmental Engineering, Nanjing Institute of Technology, Nanjing 211167, China.

Energy Research Institute, Nanjing Institute of Technology, Nanjing 211167, China.

出版信息

Nanomaterials (Basel). 2023 Feb 6;13(4):636. doi: 10.3390/nano13040636.

Abstract

Nanoflower-like MoS deposited on the surface of rectangular CaTiO(CTO) was designed and synthesized via a simple template-free strategy. Through SEM, TEM, and other characterization methods, the MoS nanoflowers were confirmed to be well deposited on the surface of CTO. LED was used as the visible light source, and rhodamine B (RhB) in an aqueous solution was used as the model pollutant to assess the photodegradation activity of the samples. The results showed that the MoS/CaTiO(MCTO) composite significantly improved the photocatalytic degradation of rhodamine B (RhB) in water, compared with a single CTO, and with the MCTO-2 composite photocatalysts, 97% degradation of RhB was achieved in 180 min, and its photocatalytic activity was about 5.17 times higher than that of the bare CTO. The main reasons for enhancing photocatalytic performance are the strong interaction between the nanoflower-like MoS and rectangular CTO, which can lead to the effective separation of electron transfer and photoexcited electron-hole pairs in MCTO composites. This work provides a new notion for researching an effective method of recycling catalytic materials.

摘要

通过一种简单的无模板策略,设计并合成了沉积在矩形钛酸钙(CTO)表面的类纳米花状二硫化钼。通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)和其他表征方法,证实二硫化钼纳米花很好地沉积在CTO表面。以发光二极管(LED)作为可见光光源,以水溶液中的罗丹明B(RhB)作为模型污染物,评估样品的光降解活性。结果表明,与单一的CTO相比,二硫化钼/钛酸钙(MCTO)复合材料显著提高了水中罗丹明B(RhB)的光催化降解性能,对于MCTO-2复合光催化剂,在180分钟内实现了97%的RhB降解,其光催化活性约为裸CTO的5.17倍。光催化性能增强的主要原因是类纳米花状二硫化钼与矩形CTO之间的强相互作用,这可导致MCTO复合材料中电子转移和光激发电子-空穴对的有效分离。这项工作为研究催化材料回收的有效方法提供了新的思路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a19/9963453/ab07a1118d6b/nanomaterials-13-00636-sch001.jpg

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