Suppr超能文献

银辅助的 Ag 嵌入姜黄素/三聚氰胺功能化磁性纳米催化剂还原硝基芳烃。

Silver-assisted reduction of nitroarenes by an Ag-embedded curcumin/melamine-functionalized magnetic nanocatalyst.

机构信息

Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114, Iran.

出版信息

Sci Rep. 2023 Mar 30;13(1):5225. doi: 10.1038/s41598-023-32560-1.

Abstract

In the current study, we introduce a hybrid magnetic nanocomposite comprised of curcumin (Cur), iron oxide magnetic nanoparticles (FeO MNPs), melamine linker (Mel), and silver nanoparticles (Ag NPs). Initially, a facile in situ route is administrated for preparing the FeO@Cur/Mel-Ag effectual magnetic catalytic system. In addition, the advanced catalytic performance of the nanocomposite to reduce the nitrobenzene (NB) derivatives as hazardous chemical substances were assessed. Nevertheless, a high reaction yield of 98% has been achieved in short reaction times 10 min. Moreover, the FeO@Cur/Mel-Ag magnetic nanocomposite was conveniently collected by an external magnet and recycled 5 times without a noticeable diminish in catalytic performance. Therefore, the prepared magnetic nanocomposite is a privileged substance for NB derivatives reduction since it achieved notable catalytic activity.

摘要

在当前的研究中,我们引入了一种由姜黄素 (Cur)、氧化铁磁性纳米粒子 (FeO MNPs)、三聚氰胺连接物 (Mel) 和银纳米粒子 (Ag NPs) 组成的混合磁性纳米复合材料。最初,采用简便的原位路线制备了 FeO@Cur/Mel-Ag 有效磁性催化体系。此外,评估了该纳米复合材料对还原作为危险化学物质的硝基苯 (NB) 衍生物的先进催化性能。然而,在短反应时间 10 分钟内,实现了高达 98%的高反应收率。此外,FeO@Cur/Mel-Ag 磁性纳米复合材料可以通过外部磁铁方便地收集,并在不明显降低催化性能的情况下循环使用 5 次。因此,由于制备的磁性纳米复合材料具有显著的催化活性,因此它是用于 NB 衍生物还原的首选物质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ba5/10063568/4d0e5f0844e1/41598_2023_32560_Sch1_HTML.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验