Department of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh, NC, USA.
Finnish Meteorological Institute, Helsinki, Finland.
Photochem Photobiol Sci. 2023 May;22(5):1177-1202. doi: 10.1007/s43630-023-00377-6. Epub 2023 Apr 11.
The deleterious effects of solar ultraviolet (UV) radiation on construction materials, especially wood and plastics, and the consequent impacts on their useful lifetimes, are well documented in scientific literature. Any future increase in solar UV radiation and ambient temperature due to climate change will therefore shorten service lifetimes of materials, which will require higher levels of stabilisation or other interventions to maintain their lifetimes at the present levels. The implementation of the Montreal Protocol and its amendments on substances that deplete the ozone layer, controls the solar UV-B radiation received on Earth. This current quadrennial assessment provides a comprehensive update on the deleterious effects of solar UV radiation on the durability of natural and synthetic materials, as well as recent innovations in better stabilising of materials against solar UV radiation-induced damage. Pertinent emerging technologies for wood and plastics used in construction, composite materials used in construction, textile fibres, comfort fabric, and photovoltaic materials, are addressed in detail. Also addressed are the trends in technology designed to increase sustainability via replacing toxic, unsustainable, legacy additives with 'greener' benign substitutes that may indirectly affect the UV stability of the redesigned materials. An emerging class of efficient photostabilisers are the nanoscale particles that include oxide fillers and nanocarbons used in high-performance composites, which provide good UV stability to materials. They also allow the design of UV-shielding fabric materials with impressive UV protection factors. An emerging environmental issue related to the photodegradation of plastics is the generation of ubiquitous micro-scale particles from plastic litter exposed to solar UV radiation.
太阳紫外线(UV)辐射对建筑材料(尤其是木材和塑料)的有害影响,以及由此对其使用寿命的影响,在科学文献中已有充分记载。因此,由于气候变化导致的太阳 UV 辐射和环境温度的任何增加,都将缩短材料的使用寿命,这将需要更高水平的稳定化或其他干预措施来维持目前的使用寿命。《蒙特利尔议定书》及其对消耗臭氧层物质的修正案的实施,控制了地球上接收到的太阳 UV-B 辐射。本次四年一度的评估全面更新了太阳紫外线辐射对天然和合成材料耐久性的有害影响,以及最近在更好地稳定材料以防止太阳紫外线辐射引起的损坏方面的创新。详细介绍了建筑中使用的木材和塑料、建筑中使用的复合材料、纺织纤维、舒适织物和光伏材料的相关新兴技术。还介绍了通过用“更环保”的良性替代品替代有毒、不可持续的传统添加剂来提高可持续性的技术趋势,这些替代品可能会间接影响重新设计材料的紫外线稳定性。一类新兴的高效光稳定剂是纳米级颗粒,包括用于高性能复合材料的氧化物填料和纳米碳,它们为材料提供了良好的紫外线稳定性。它们还允许设计具有令人印象深刻的紫外线防护因子的防紫外线织物材料。与塑料光降解有关的一个新兴环境问题是,暴露于太阳紫外线辐射的塑料垃圾会产生无处不在的微尺度颗粒。