Zhao Ruiqi, Wang Mengli, Guan Xuemao
School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, China.
Materials (Basel). 2023 Apr 2;16(7):2830. doi: 10.3390/ma16072830.
Chloride ion attack is a major cause of concrete durability problems, and existing studies have rarely addressed the effects of damage zones. In this paper, an improved mesoscale model including five phases was constructed using the finite element software ABAQUS to study the diffusivity of chloride ions in cracked concrete. It was found that the damage zone is negligible when the crack width is less than 50 μm, while the width and depth of the damage zone are about 15 times the crack width and 15% of the crack depth when the crack is greater than 50 μm. The results show that the diffusion of chloride is greatly influenced by the crack width, while it is little-influenced by the crack shape. Low water-cement ratio and adequate hydration of the concrete are also key factors affecting chloride diffusion. In contrast, regular rounded aggregates have a positive effect on reducing chloride diffusion compared to irregularly shaped aggregates, and this effect becomes weaker with increasing service time. In addition, the protective layer can effectively prevent the diffusion of chloride in concrete. Therefore, when designing marine concrete, efforts should be made to ensure that the concrete has a low water-cement ratio, adequate hydration, less cracking and a protective layer.
氯离子侵蚀是导致混凝土耐久性问题的主要原因,而现有研究很少涉及损伤区域的影响。本文利用有限元软件ABAQUS构建了一个包含五个相的改进细观模型,以研究氯离子在开裂混凝土中的扩散系数。研究发现,当裂缝宽度小于50μm时,损伤区域可忽略不计;而当裂缝宽度大于50μm时,损伤区域的宽度和深度分别约为裂缝宽度的15倍和裂缝深度的15%。结果表明,氯离子扩散受裂缝宽度影响较大,而受裂缝形状影响较小。低水灰比和混凝土充分水化也是影响氯离子扩散的关键因素。相比之下,规则圆形集料比不规则形状集料对减少氯离子扩散有积极作用,且这种作用随着服役时间的增加而减弱。此外,保护层能有效阻止混凝土中氯离子的扩散。因此,在设计海工混凝土时,应努力确保混凝土具有低水灰比、充分水化、较少裂缝和保护层。