Yi Youqiu, Chen Yifan, Shi Shuo, Zhao Yao, Wang Daming, Lei Tao, Duan Pengpeng, Cao Weiwei, Wang Qiang, Li Haitao
College of Civil Engineering, Nanjing Forestry University, Nanjing 210037, China.
Nanjing Freetech Road Recycling Co., Ltd., Nanjing 320100, China.
Polymers (Basel). 2023 Mar 30;15(7):1718. doi: 10.3390/polym15071718.
Rice husk biochar (RHB) is a renewable agricultural waste, and its fixation on pavements helps develop environmentally friendly, economical, and sustainable asphalt pavements. This paper used RHB to replace part of styrene-butadiene-styrene (SBS) for the composite modification study of matrix asphalt. The high- and low-temperature properties and microscopic mechanisms of the composite-modified asphalt were studied through a series of tests. The results showed that, compared with SBS-modified asphalt, the softening point, viscosity, complex shear modulus, stiffness modulus, and rutting factors of RHB-SBS composite-modified asphalt were improved. In contrast, the ductility and creep rate were slightly decreased, indicating an improvement in the high-temperature performance of composite-modified asphalt, but a slight decrease in its low-temperature performance. The process of RHB and SBS composite modification was mainly physical blending, with only a small number of chemical reactions, and no new functional groups were generated. The porous structure of RHB enables it to adhere better to the network crosslinked continuous phase system formed by SBS and matrix asphalt. This results in composite-modified asphalt with good high-temperature storage stability and rheological properties. Therefore, RHB-SBS composite-modified asphalt can be applied to high-temperature areas and rice-producing areas, and the optimal content of RHB is suggested to be 15%.
稻壳生物炭(RHB)是一种可再生农业废弃物,将其用于路面固定有助于开发环保、经济且可持续的沥青路面。本文采用RHB替代部分苯乙烯-丁二烯-苯乙烯(SBS)对基质沥青进行复合改性研究。通过一系列试验研究了复合改性沥青的高低温性能及微观机理。结果表明,与SBS改性沥青相比,RHB-SBS复合改性沥青的软化点、粘度、复数剪切模量、劲度模量和车辙因子均有所提高。相比之下,延度和蠕变速率略有降低,表明复合改性沥青的高温性能有所改善,但其低温性能略有下降。RHB与SBS的复合改性过程主要是物理共混,仅有少量化学反应,未产生新的官能团。RHB的多孔结构使其能更好地粘附于由SBS和基质沥青形成的网络交联连续相体系。这使得复合改性沥青具有良好的高温储存稳定性和流变性能。因此,RHB-SBS复合改性沥青可应用于高温地区和水稻产区,建议RHB的最佳含量为15%。