无过渡金属促进的 2,5-呋喃二甲酸合成的放大及反应机理研究。
Transition-Metal-Free Upscaling of 2,5-Furandicarboxylic Acid Synthesis and Investigation of the Reaction Mechanism.
机构信息
Department of Energy Science, Sungkyunkwan University, Suwon, 16419, South Korea.
Chemical Research Center, Samyang Corp., Daejeon, 34055, South Korea.
出版信息
Chemistry. 2023 Jun 27;29(36):e202300903. doi: 10.1002/chem.202300903. Epub 2023 May 3.
An environmentally friendly oxidation system has proposed for the practical and scalable production of value-added 2,5-furandicarboxylic acid from 1 kg of 5-hydroxymethylfurfural. The system is composed of a simple base, oxygen, and a green solvent, thereby providing a sustainable and economical approach to organic synthesis. To gain insight into the mechanism of this oxidation process, NMR spectroscopic analysis and kinetic study are used for the mechanistic investigation of this environmentally friendly oxidation process.
提出了一种环保的氧化体系，用于从 1kg 5-羟甲基糠醛实际且规模化制备高附加值的 2,5-呋喃二甲酸。该体系由一种简单的碱、氧气和一种绿色溶剂组成，为有机合成提供了一种可持续且经济的方法。为了深入了解该氧化过程的机理，采用 NMR 光谱分析和动力学研究对该环保氧化过程的机理进行了研究。
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