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多孔介质处理含油污泥的可行性研究,采用自维持处理技术进行主动修复。

Feasibility study of porous media for treating oily sludge with self-sustaining treatment for active remediation technology.

机构信息

Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun, 130021, China.

National and Local Joint Engineering Laboratory for Petrochemical Contaminated Site Control and Remediation Technology, Jilin University, 2519 Jiefang Road, Changchun, 130021, China.

出版信息

Environ Sci Pollut Res Int. 2023 Jun;30(27):70131-70142. doi: 10.1007/s11356-023-27196-7. Epub 2023 May 5.

Abstract

Oil sludge is the primary pollutant produced by the petroleum industry, which is characterized by large quantities, difficult disposal, and high toxicity. Improper treatment of oil sludge will pose a severe threat to the human living environment. Self-sustaining treatment for active remediation (STAR) technology has a specific potential for treating oil sludge, with low energy consumption, short remediation time, and high removal efficiency. Given the low smoldering porosity, poor air permeability, and poor repair effect of oil sludge, this paper considered coarse river sand as the porous medium, built a smoldering reaction device, conducted a comparative study on smoldering experiments of oil sludge with and without river sand, and studied the key factors affecting smoldering of oil sludge. The study shows that the repair effect is greatly improved by adding river sand, increasing the pore, and improving air permeability, and the total petroleum hydrocarbon removal rate reaches more than 98%, which meets the requirements of oil sludge treatment. When the mass ratio of oil sludge to river sand (sludge-sand ratio) is 2:1, the flow velocity is 5.39 cm/s, and the particle size of the medium is 2-4 mm. In addition, the best conditions for smoldering occur. The average peak temperature, average propagation speed, and average removal efficiency are relatively high. The peak temperature occurs in a short time; the heating time is also short, and the heat loss is low. Moreover, the generation of toxic and harmful gases is reduced, and secondary pollution is hindered. The experiment indicates that the porous media play a crucial role in the smoldering combustion of oil sludge.

摘要

油泥是石油工业产生的主要污染物,具有数量多、处理难、毒性大的特点。油泥如果处理不当,会对人类的生存环境造成严重威胁。自维持主动修复(STAR)技术在处理油泥方面具有特定的潜力,其具有能耗低、修复时间短、去除效率高等特点。由于油泥的闷烧孔隙率低、透气性差、修复效果差,本文考虑以粗河砂作为多孔介质,构建闷烧反应装置,对油泥进行有无河砂条件下的闷烧实验对比研究,研究影响油泥闷烧的关键因素。研究表明,通过添加河砂增加孔隙度和改善透气性,可以大大提高修复效果,总石油烃去除率达到 98%以上,满足油泥处理要求。当油泥与河砂的质量比(泥砂比)为 2:1,流速为 5.39cm/s,介质粒径为 2-4mm 时,闷烧条件最佳。平均峰值温度、平均传播速度和平均去除效率均较高。峰值温度出现在短时间内;加热时间也较短,热损失较低。此外,还减少了有毒有害气体的产生,阻碍了二次污染。实验表明,多孔介质在油泥闷烧燃烧中起着至关重要的作用。

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