新型可溶性β-取代氯氟醇锌酞菁衍生物的合成与表征。
Synthesis and Characterization of New-Type Soluble β-Substituted Zinc Phthalocyanine Derivative of Clofoctol.
机构信息
Experimental Sciences and Supramolecular Chemistry, Laboratory of Didactic Research, Higher Institute of Education and Continuing Training (ISEFC), University of Tunis El Manar, Tunis 1002, Tunisia.
Experimental Sciences and Supramolecular Chemistry, Laboratory of Didactic Research, Higher Institute of Education and Continuing Training (ISEFC), University of Carthage, Tunis 1054, Tunisia.
出版信息
Molecules. 2023 May 15;28(10):4102. doi: 10.3390/molecules28104102.
In this work, we have described the synthesis and characterization of novel zinc (II) phthalocyanine bearing four 2-(2,4-dichloro-benzyl)-4-(1,1,3,3-tetramethyl-butyl)-phenoxy substituents on the peripheral positions. The compound was characterized by elemental analysis and different spectroscopic techniques, such as FT-IR, H NMR, MALDI-TOF, and UV-Vis. The Zn (II) phthalocyanine shows excellent solubility in organic solvents such as dichloromethane (DCM), n-hexane, chloroform, tetrahydrofuran (THF), and toluene. Photochemical and electrochemical characterizations of the complex were performed by UV-Vis, fluorescence spectroscopy, and cyclic voltammetry. Its good solubility allows a direct deposition of this compound as film, which has been tested as a solid-state sensing material in gravimetric chemical sensors for gas detection, and the obtained results indicate its potential for qualitative discrimination and quantitative assessment of various volatile organic compounds, among them methanol, n-hexane, triethylamine (TEA), toluene and DCM, in a wide concentration range.
在这项工作中，我们描述了新型锌（II）酞菁的合成与表征，该化合物在其外围位置带有四个 2-(2,4-二氯苄基）-4-(1,1,3,3-四甲基丁基）-苯氧基取代基。该化合物通过元素分析和不同的光谱技术（如 FT-IR、H NMR、MALDI-TOF 和 UV-Vis）进行了表征。锌（II）酞菁在有机溶剂如二氯甲烷（DCM）、正己烷、氯仿、四氢呋喃（THF）和甲苯中具有优异的溶解性。通过 UV-Vis、荧光光谱和循环伏安法对配合物进行了光化学和电化学表征。其良好的溶解性使其能够直接作为薄膜沉积，已将其作为固态传感材料用于气相检测的重量化学传感器中进行测试，得到的结果表明其具有定性区分和定量评估各种挥发性有机化合物（包括甲醇、正己烷、三乙胺（TEA）、甲苯和 DCM）的潜力，浓度范围很宽。
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