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可见光下通过 SnO/rGO 复合材料光催化降解有机污染物和灭活病原体。

Photocatalytic degradation of organic pollutants and inactivation of pathogens under visible light via SnO/rGO composites.

机构信息

Department of Conservative Dentistry and Endodontics, Saveetha Dental College and Hospitals, Saveetha Institute of Medical and Technical Sciences (SIMATS), Chennai, 600 077, India.

School of Chemical Engineering, Yeungnam University, 280 Daehak-Ro, Gyeongsan, 38541, Republic of Korea.

出版信息

Chemosphere. 2023 Sep;335:139102. doi: 10.1016/j.chemosphere.2023.139102. Epub 2023 Jun 6.

Abstract

The domains of environmental cleanup and pathogen inactivation are particularly interesting in nanocomposites (NCs) due to their exceptional physicochemical properties. Tin oxide/reduced graphene oxide nanocomposites (SnO/rGO NCs) have potential uses in the biological and environmental fields, but little is known about them. This study aimed to investigate the photocatalytic activity and antibacterial efficiency of the nanocomposites. The co-precipitation technique was used to prepare all the samples. XRD, SEM, EDS, TEM, and XPS analyses were employed to characterize the physicochemical properties of SnO/rGO NCs for structural analysis. The rGO loading sample resulted in a decrease in the crystallite size of SnO nanoparticles. TEM and SEM images demonstrate the firm adherence of SnO nanoparticles to the rGO sheets. The chemical state and elemental composition of the nanocomposites were validated by the XPS and EDS data. Additionally, the visible-light active photocatalytic and antibacterial capabilities of the synthesized nanocomposites were assessed for the degradation of Orange II and methylene blue, as well as the suppression of the growth of S. aureus and E. coli. As a result, the synthesized SnO/rGO NCs are improved photocatalysts and antibacterial agents, expanding their potential in the fields of environmental remediation and water disinfection.

摘要

由于具有特殊的物理化学性质,环境清理和病原体失活领域在纳米复合材料(NCs)中特别有趣。氧化锡/还原氧化石墨烯纳米复合材料(SnO/rGO NCs)在生物和环境领域具有潜在的用途,但人们对此知之甚少。本研究旨在研究纳米复合材料的光催化活性和抗菌效率。采用共沉淀技术制备了所有样品。XRD、SEM、EDS、TEM 和 XPS 分析用于对 SnO/rGO NCs 的物理化学性质进行结构分析。rGO 负载样品导致 SnO 纳米颗粒的晶粒度减小。TEM 和 SEM 图像表明 SnO 纳米颗粒牢固地附着在 rGO 片上。XPS 和 EDS 数据验证了纳米复合材料的化学状态和元素组成。此外,评估了合成纳米复合材料对橙色 II 和亚甲基蓝的可见光活性光催化和抗菌能力,以及对金黄色葡萄球菌和大肠杆菌生长的抑制作用。结果表明,合成的 SnO/rGO NCs 是改良的光催化剂和抗菌剂,扩大了它们在环境修复和水消毒领域的应用潜力。

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