Bărar Ana, Maclean Stephen Akwei, Dănilă Octavian, Taylor André D
Electronic Technology and Reliability Department, Polytechnic University of Bucharest, 060082 Bucharest, Romania.
Chemical Engineering Department, Tandon School of Engineering, New York University, Brooklyn, NY 11201, USA.
Materials (Basel). 2023 May 24;16(11):3934. doi: 10.3390/ma16113934.
Reflective loss is one of the main factors contributing to power conversion efficiency limitation in thin-film perovskite solar cells. This issue has been tackled through several approaches, such as anti-reflective coatings, surface texturing, or superficial light-trapping metastructures. We report detailed simulation-based investigations on the photon trapping capabilities of a standard Methylammonium Lead Iodide (MAPbI3) solar cell, with its top layer conveniently designed as a fractal metadevice, to reach a reflection value R<0.1 in the visible domain. Our results show that, under certain architecture configurations, reflection values below 0.1 are obtained throughout the visible domain. This represents a net improvement when compared to the 0.25 reflection yielded by a reference MAPbI3 having a plane surface, under identical simulation conditions. We also present the minimum architectural requirements of the metadevice by comparing it to simpler structures of the same family and performing a comparative study. Furthermore, the designed metadevice presents low power dissipation and exhibits approximately similar behavior regardless of the incident polarization angle. As a result, the proposed system is a viable candidate for being a standard requirement in obtaining high-efficiency perovskite solar cells.
反射损耗是导致薄膜钙钛矿太阳能电池功率转换效率受限的主要因素之一。这个问题已经通过多种方法解决,比如抗反射涂层、表面纹理化或表面光捕获亚结构。我们报告了基于详细模拟的对标准甲基碘化铅(MAPbI3)太阳能电池光子捕获能力的研究,其顶层被巧妙设计为分形超构器件,以在可见光域达到反射值R<0.1。我们的结果表明,在某些结构配置下,在整个可见光域都能获得低于0.1的反射值。与在相同模拟条件下具有平面表面的参考MAPbI3产生的0.25反射相比,这代表了明显的改善。我们还通过将超构器件与同一家族的更简单结构进行比较并开展对比研究,给出了超构器件的最低结构要求。此外,所设计的超构器件呈现出低功耗,并且无论入射偏振角如何都表现出大致相似的行为。因此,所提出的系统是成为获得高效钙钛矿太阳能电池标准要求的一个可行候选方案。