Si Tiantian, Xie Shuai, Ji Zhijiang, Wu Zihao, Ma Chao, Wu Junyu, Wang Jing
China Building Materials Academy, Beijing 100024, People's Republic of China.
State Key Laboratory of Green Building Materials, Beijing 100024, People's Republic of China.
Nanotechnology. 2023 Jul 19;34(40). doi: 10.1088/1361-6528/ace365.
The development of practical and efficient electromagnetic wave (EMW) absorbing materials is a challenging research problem. A mussel-inspired molecular structure regulation strategy using polydopamine to increase the roughness and functional groups of basalt fiber (BF) surface, which can improve the fiber interfacial adhesion. Herein, a novel BF-FeO/CNTs heterostructure is synthesized through a dip-coating adsorption process. The three-dimensional network structure of FeO/CNTs hybridanchored on the surface of BF, which endows the composite to have good intrinsic magnetic and dielectric properties. Modulation of EMW absorption performance by controlling the addition of CNTs, the minimum RL of BF-FeO/7C reaches to -40.57 dB at a thickness of 1.5 mm with CNTs addition of 7%. The enhanced EMW absorption performance of BF-FeO/7C heterostructure may be attributed to the synergistic effects of interfacial polarization between the hollow magnetic FeOspheres and CNTs, conduction loss, magnetic resonance loss and multiple reflection/scattering inside the BF. This work provides a simple pathway to design EMW absorbing materials with good environmental stability.
开发实用且高效的电磁波吸收材料是一个具有挑战性的研究课题。一种受贻贝启发的分子结构调控策略,利用聚多巴胺增加玄武岩纤维(BF)表面的粗糙度和官能团,这可以改善纤维界面附着力。在此,通过浸涂吸附工艺合成了一种新型的BF-FeO/碳纳米管(CNTs)异质结构。FeO/CNTs杂化物的三维网络结构锚定在BF表面,这赋予复合材料良好的本征磁性能和介电性能。通过控制CNTs的添加量来调节电磁波吸收性能,当CNTs添加量为7%时,BF-FeO/7C在厚度为1.5 mm时的最小反射损耗(RL)达到-40.57 dB。BF-FeO/7C异质结构增强的电磁波吸收性能可能归因于空心磁性FeO球与CNTs之间的界面极化、传导损耗、磁共振损耗以及BF内部的多次反射/散射的协同效应。这项工作为设计具有良好环境稳定性的电磁波吸收材料提供了一条简单途径。