Hussain Javid, Kim Dae-Kyeom, Park Sangmin, Khalid Muhammad-Waqas, Hussain Sayed-Sajid, Lee Bin, Song Myungsuk, Kim Taek-Soo
Industrial Technology, University of Science and Technology, Daejeon 34113, Republic of Korea.
Korea Institute for Rare Metals, Korea Institute of Industrial Technology, Incheon 21999, Republic of Korea.
Materials (Basel). 2023 Jun 21;16(13):4515. doi: 10.3390/ma16134515.
Proton exchange membrane fuel cell (PEMFC) is a renewable energy source rapidly approaching commercial viability. The performance is significantly affected by the transfer of fluid, charges, and heat; gas diffusion layer (GDL) is primarily concerned with the consistent transfer of these components, which are heavily influenced by the material and design. High-efficiency GDL must have excellent thermal conductivity, electrical conductivity, permeability, corrosion resistance, and high mechanical characteristics. The first step in creating a high-performance GDL is selecting the appropriate material. Therefore, titanium is a suitable substitute for steel or carbon due to its high strength-to-weight and superior corrosion resistance. The second crucial parameter is the fabrication method that governs all the properties. This review seeks to comprehend numerous fabrication methods such as tape casting, 3D printing, freeze casting, phase separation technique, and lithography, along with the porosity controller in each process such as partial sintering, input design, ice structure, pore agent, etching time, and mask width. Moreover, other GDL properties are being studied, including microstructure and morphology. In the future, GeoDict simulation is highly recommended for optimizing various GDL properties, as it is frequently used for other porous materials. The approach can save time and energy compared to intensive experimental work.
质子交换膜燃料电池(PEMFC)是一种正迅速接近商业可行性的可再生能源。其性能受到流体、电荷和热量传输的显著影响;气体扩散层(GDL)主要涉及这些组分的持续传输,而这些组分受到材料和设计的严重影响。高效的GDL必须具有优异的热导率、电导率、渗透率、耐腐蚀性以及高机械性能。制造高性能GDL的第一步是选择合适的材料。因此,钛因其高强度重量比和卓越的耐腐蚀性,是钢或碳的合适替代品。第二个关键参数是控制所有性能的制造方法。本综述旨在了解诸如流延成型、3D打印、冷冻铸造、相分离技术和光刻等多种制造方法,以及每个过程中的孔隙率控制因素,如部分烧结、输入设计、冰结构、造孔剂、蚀刻时间和掩膜宽度。此外,正在研究GDL的其他性能,包括微观结构和形态。未来,强烈推荐使用GeoDict模拟来优化GDL的各种性能,因为它经常用于其他多孔材料。与大量的实验工作相比,这种方法可以节省时间和精力。