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注塑包覆成型参数对热固性-热塑性混合复合材料界面粘结强度的影响

Effect of Injection Overmolding Parameters on the Interface Bonding Strength of Hybrid Thermoset-Thermoplastic Composites.

作者信息

Miao Tianyu, Wang Wenhao, Zhai Zhanyu, Ding Yudong

机构信息

College of Mechanical and Electrical Engineering, Central South University, Changsha 410083, China.

State Key Laboratory of Precision Manufacturing for Extreme Service Performance, Central South University, Changsha 410083, China.

出版信息

Polymers (Basel). 2023 Jun 29;15(13):2879. doi: 10.3390/polym15132879.

Abstract

In this study, the thermoset-thermoplastic structure was produced through a co-curing technique together with an injection overmolding technique. Continuous fiber reinforced thermoset composite (TSC) was selected as thermoset material, while polyamide 6 (PA 6) was chosen as thermoplastic material. The influence of injection temperature, preheating temperature and injection speed on the interfacial bonding strength of hybrid thermoset-thermoplastic composites was investigated. The results show that increasing injection temperature and preheating temperature have significant effects on the increase in bonding strength, while injection speed has little effect on it. In addition, the bonding strength of the co-cured interface is enhanced after the injection overmolding process, which is further studied through molecular dynamic (MD) simulation. The molecular dynamic simulation result shows that the high temperature and pressure during the injection process only have a weak effect on enhancing the bonding strength of the co-cured interface, while the chemical reaction at the co-cured interface is the main reason for the enhancement. Furthermore, the more chemical reactions occur at the interface, the stronger the interface will be.

摘要

在本研究中,热固性-热塑性结构是通过共固化技术与注塑包覆成型技术共同制备的。连续纤维增强热固性复合材料(TSC)被选为热固性材料,而聚酰胺6(PA 6)被选为热塑性材料。研究了注射温度、预热温度和注射速度对热固性-热塑性混杂复合材料界面粘结强度的影响。结果表明,提高注射温度和预热温度对粘结强度的增加有显著影响,而注射速度对其影响较小。此外,注塑包覆成型过程后,共固化界面的粘结强度得到增强,通过分子动力学(MD)模拟对此进行了进一步研究。分子动力学模拟结果表明,注射过程中的高温高压对增强共固化界面的粘结强度作用较弱,而共固化界面处的化学反应是强度增强的主要原因。此外,界面处发生的化学反应越多,界面就越强。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b7c2/10347229/04c690af7e71/polymers-15-02879-g001.jpg

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