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中国滇西北地区矿区、采石场及其他特殊区域土壤重金属分布特征、来源分析及风险评价

Heavy metals distribution characteristics, source analysis, and risk evaluation of soils around mines, quarries, and other special areas in a region of northwestern Yunnan, China.

机构信息

College of Pharmacy, Dali University, Dali, Yunnan 671000, China.

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.

出版信息

J Hazard Mater. 2023 Sep 15;458:132050. doi: 10.1016/j.jhazmat.2023.132050. Epub 2023 Jul 12.

Abstract

In this study, based on the assessment of soil heavy metals (HMs) pollution using relevant indices, a comprehensive approach combined network environ analysis (NEA), human health risk assessment (HHRA) method and positive definite matrix factor (PMF) model to quantify the risks among ecological communities in a special environment around mining area in northwest Yunnan, calculated the risk to human health caused by HMs in soil, and analyzed the pollution sources of HMs. The integrated risks for soil microorganisms, vegetations, herbivores, and carnivores were 2.336, 0.876, 0.114, and 0.082, respectively, indicating that soil microorganisms were the largest risk receptors. The total hazard indexes (HI) for males, females, and children were 0.542, 0.591, and 1.970, respectively, revealing a relatively high and non-negligible non-carcinogenic risks (NCR) for children. The total cancer risks (TCR) for both females and children exceeded 1.00E-04, indicating that soil HMs posed carcinogenic risks (CR) to them. Comparatively, Pb was the high-risk metal, accounting for 53.76%, 57.90%, and 68.09% of HI in males, females, and children, respectively. PMF analysis yielded five sources of pollution, F1 (industry), F2 (agriculture), F3 (domesticity), F4 (nature), and F5 (traffic).

摘要

本研究采用相关指数评估土壤重金属(HMs)污染,结合网络环境分析(NEA)、人体健康风险评估(HHRA)方法和正定矩阵因子(PMF)模型,对滇西北矿区特殊环境中生态群落的风险进行量化,计算土壤中 HMs 对人体健康的危害,并分析 HMs 的污染源。土壤微生物、植被、草食动物和肉食动物的综合风险分别为 2.336、0.876、0.114 和 0.082,表明土壤微生物是最大的风险受体。男性、女性和儿童的总危害指数(HI)分别为 0.542、0.591 和 1.970,表明儿童存在较高且不可忽视的非致癌风险(NCR)。女性和儿童的总癌症风险(TCR)均超过 1.00E-04,表明土壤 HMs 对其具有致癌风险(CR)。相比之下,Pb 是高风险金属,占男性、女性和儿童 HI 的 53.76%、57.90%和 68.09%。PMF 分析得到了五个污染源,F1(工业)、F2(农业)、F3(家庭)、F4(自然)和 F5(交通)。

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