含咪唑侧链的聚对二甲苯纳米薄膜的纳滤性能
Nanofiltration Performance of Poly(-xylylene) Nanofilms with Imidazole Side Chains.
作者信息
Yoshida Satsuki, Shii Takeshi, Kitazawa Yu, Kim Manuela L, Otal Eugenio H, Hattori Yoshiyuki, Kimura Mutsumi
机构信息
Department of Chemistry and Materials, Faculty of Textile Science and Technology, Shinshu University, Ueda 386-8567, Japan.
Research Initiative for Supra-Materials (RISM), Interdisciplinary Cluster for Cutting Edge Research (ICCER), Shinshu University, Ueda 386-8567, Japan.
出版信息
Polymers (Basel). 2023 Aug 4;15(15):3309. doi: 10.3390/polym15153309.
Herein, we report the nanofiltration performance of poly(-xylylene) thin films with imidazole side chains that were deposited onto commercial polyethersulfone ultrafiltration membranes using a chemical vapor deposition process. The resulting thin films with a few tens of nanometers exhibited water permeation under a pressure difference of 0.5 MPa and selectively rejected water-soluble organic dyes based on their molecular sizes. Additionally, thin flaky ZIF-L crystals (Zn(mim)·(Hmim)·(HO)) (Hmim = 2-methylimidazole) formed on the surface of imidazole-containing poly(-xylylene) films, and the composite films demonstrated the ability to adsorb methylene blue molecules within the cavities of ZIF-L.
在此，我们报告了通过化学气相沉积工艺沉积在商用聚醚砜超滤膜上的带有咪唑侧链的聚（对二甲苯）薄膜的纳滤性能。所得几十纳米厚的薄膜在0.5 MPa的压差下表现出透水性能，并根据分子大小选择性截留水溶性有机染料。此外，在含咪唑的聚（对二甲苯）薄膜表面形成了薄片状的ZIF-L晶体（Zn(mim)·(Hmim)·(HO)）（Hmim = 2-甲基咪唑），并且复合薄膜表现出在ZIF-L的孔腔内吸附亚甲基蓝分子的能力。
Zotero 插件