Kanwal Ayesha, Rehman Rabia, Imran Muhammad, Samin Ghufrana, Jahangir Muhammad Muzammil, Ali Saadat
Centre for Inorganic Chemistry, School of Chemistry, University of the Punjab Quaid-e-Azam Campus Lahore-54590 Pakistan
Department of Basic Sciences and Humanities, University of Engineering and Technology (Lahore) Faisalabad Campus Pakistan
RSC Adv. 2023 Sep 5;13(38):26455-26474. doi: 10.1039/d3ra02104a. eCollection 2023 Sep 4.
Persistent organic pollutants and dyes cause major problems during ecofriendly wastewater treatment. To overcome this huge problem, several techniques have been considered and in practice for the safe disposal of organic pollutants in recent years; some of them are discussed and compared herein. This review focuses on new trends for wastewater treatment and compares them with certain other techniques alongside their pros and cons; adsorption is considered the safest among them. Adsorbents derived from agri-wastes have good capacity for the removal of these contaminants owing to their great sorption capacity, high reusability, easy operation, Sometimes they need some modifications for the removal of dyes, which are also discussed in this review. This capacity of adsorbents to chelate dye molecules can be affected by factors, such as pH, the concentration of dyes and adsorbents, and temperature of the system. pH has direct influence on the ionization potential and charge on the outer surface of adsorbents. The findings on isotherms, kinetics, and desorption of plant waste-based biomaterials that are safe for the ecosystem and user friendly and are used for hazardous contaminant removal from water are summarized in this review. Finally, conclusions and future perspectives are presented, and some other materials, such as CNTs and MOFs, are also discussed as efficient adsorbents for eliminating dyes from wastewater. Finally, it is predicted that the adsorption of dyes is a more feasible solution for this dye pollution problem.
持久性有机污染物和染料在生态友好型废水处理过程中会引发重大问题。为克服这一巨大难题,近年来人们考虑并实践了多种技术用于有机污染物的安全处置;本文将对其中一些技术进行讨论和比较。本综述聚焦于废水处理的新趋势,并将它们与其他特定技术进行比较,同时阐述其优缺点;其中吸附被认为是最安全的方法。源自农业废弃物的吸附剂因其强大的吸附能力、高可重复使用性、操作简便,对去除这些污染物具有良好的效果。有时它们需要进行一些改性以去除染料,本综述也对此进行了讨论。吸附剂螯合染料分子的能力会受到诸如pH值、染料和吸附剂浓度以及系统温度等因素的影响。pH值对吸附剂外表面的电离势和电荷有直接影响。本综述总结了基于植物废弃物的生物材料在等温吸附、动力学和脱附方面的研究结果,这些生物材料对生态系统安全且用户友好,用于从水中去除有害污染物。最后,给出了结论和未来展望,并讨论了一些其他材料,如碳纳米管和金属有机框架材料,作为从废水中去除染料的高效吸附剂。最后,预测吸附染料是解决这一染料污染问题更可行的方案。