Environmental forensics approach to source investigation in a mercury contaminated river: Insights from mercury stable isotopes.

Environmental forensics approach was applied to assess the efficacy of mercury (Hg) stable isotopes for source screening and decision-making in the Hyeongsan River, South Korea. Four Hg contamination scenarios were identified- atmospheric Hg emissions from a steel manufacturing industry, upstream riverine Hg transport, and industrial Hg releases and historical landfill collapse from Gumu Creek. The absence of significant Hg isotope difference between the Hyeongsan River sediments (δHg; -0.46 ± 0.17‰, ΔHg; -0.04 ± 0.06‰) and the Gumu Creek sediment (δHg; -0.39 ± 0.26‰, ΔHg; -0.04 ± 0.03‰) confirm that Hg source is originated from Gumu Creek. The heterogeneous Hg distribution throughout Gumu Creek and statistically similar Hg isotope ratios between Gumu Creek and solid waste cores from the landfill suggests that the landfill collapse is the dominant source to the Hyeongsan-Gumu system. Present Hg releases is also possible given the elevated and matching ΔHg between some riverine sediments and wastewater sampled from the landfill. The ternary mixing model estimates that the landfill collapse and wastewater releases contribute 61 ± 25 % and 22 ± 11 %, and the regional background, reflecting terrestrial runoff using deep sediment cores, explain 17 ± 24 % of Hg to the riverine sediment. We suggest that Hg isotopes can be used for routine source screening in areas where Hg sources are unknown.