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通过浮选从菱镁矿中去除硅:粒度的影响及机械机制

Removal of Silicon from Magnesite by Flotation: Influence of Particle Size and Mechanical Mechanism.

作者信息

Zhang Ruinan, Liu Zhaoyang, Yu Jingkun

机构信息

School of Metallurgy, Northeastern University, Shenyang 110819, China.

Key Laboratory for Ecological Metallurgy of Multimetallic Mineral, Ministry of Education, Shenyang 110819, China.

出版信息

Materials (Basel). 2023 Sep 6;16(18):6095. doi: 10.3390/ma16186095.

Abstract

The feasibility of producing high-density sintered magnesia with a one-step sintering method was investigated by utilizing finely ground magnesite as raw materials for direct flotation. The mechanism of flotation desilication of microfine grain magnesite was investigated by combining microstructure and chemical properties. The results showed that dodecylamine (DDA) has a sorting effect on magnesite reverse flotation desilication. Under the premise of 150 mg/L sodium polyacrylate (PAANa) as an inhibitor and 300 mg/L DDA as a collector, the content and recovery rate of MgO can reach 83.91% and 78.78%, respectively. When sodium oleate (NaOL) was used as a collector, the recovery rate of MgO was only 49.22%; therefore, it is unsuitable for magnesite purification. The flotation effect was affected because MgO particles and SiO particles agglomerated in the flotation process. The flotation agent cannot work for a single element but works for the mineral agglomerate. While collecting Si elements, the agglomerated MgO was also brought into the froth layer, making flotation impossible.

摘要

以细磨菱镁矿为原料,采用一步烧结法制备高密度烧结氧化镁的可行性进行了研究,用于直接浮选。通过结合微观结构和化学性质,研究了微细粒菱镁矿的浮选脱硅机理。结果表明,十二胺(DDA)对菱镁矿反浮选脱硅有分选作用。在150mg/L聚丙烯酸钠(PAANa)作为抑制剂和300mg/L DDA作为捕收剂的前提下,MgO的含量和回收率分别可达83.91%和78.78%。当油酸钠(NaOL)作为捕收剂时,MgO的回收率仅为49.22%;因此,它不适用于菱镁矿提纯。由于MgO颗粒和SiO颗粒在浮选过程中团聚,影响了浮选效果。浮选药剂不是对单一元素起作用,而是对矿物团聚体起作用。在收集Si元素时,团聚的MgO也被带入泡沫层,导致无法浮选。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/89c0/10532998/6796b19c124c/materials-16-06095-g001.jpg

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