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一种制备有机发光材料的超分子组装策略。

A supramolecular assembly strategy towards organic luminescent materials.

作者信息

Yin Chenjia, Yan Zi-Ang, Ma Xiang

机构信息

Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Meilong Road 130, Shanghai 200237, P. R. China.

出版信息

Chem Commun (Camb). 2023 Nov 9;59(90):13421-13433. doi: 10.1039/d3cc04051h.

Abstract

Supramolecular organic luminescent materials with different dimensionalities usually exhibit different optical properties as well as their potential applications in various fields. Recent reports showed that non-covalent interactions are useful tools to obtain diverse luminescent materials due to their dynamicity and reversibility, including π-π stacking, host-guest interactions, hydrophobic effects, hydrogen bonding, electrostatic effects and so on. In this review, we summarized recent progress in zero-, one-, two-, three-dimensional and disordered organic luminescent materials using the aforementioned strategies, in order to provide a solution for designing luminescent materials with specific structures and morphologies. The relationship between assembly behavior and luminescent properties is discussed in detail, along with the existing difficulties hindering the development of supramolecular assembly systems and future research directions.

摘要

具有不同维度的超分子有机发光材料通常表现出不同的光学性质以及它们在各个领域的潜在应用。最近的报道表明,非共价相互作用由于其动态性和可逆性,是获得多种发光材料的有用工具,包括π-π堆积、主客体相互作用、疏水效应、氢键、静电效应等。在这篇综述中,我们总结了使用上述策略在零维、一维、二维、三维和无序有机发光材料方面的最新进展,以便为设计具有特定结构和形态的发光材料提供解决方案。详细讨论了组装行为与发光性质之间的关系,以及阻碍超分子组装体系发展的现有困难和未来的研究方向。

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