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用于工业废水处理的膜生物反应器中改性中空纤维膜载银纳米颗粒-沸石Na-Y/PVDF复合材料的性能

Performance of modified hollow fiber membrane silver nanoparticles-zeolites Na-Y/PVDF composite used in membrane bioreactor for industrial wastewater treatment.

作者信息

Darmayanti Rizki Fitria, Muharja Maktum, Widjaja Arief, Widiastuti Nurul, Rachman Rahadian Abdul, Widyanto Alvin Rahmad, Halim Abdul, Satrio Dendy, Piluharto Bambang

机构信息

Department of Agro-industrial Technology, Faculty of Agriculture, Universitas Muhammadiyah Jember, Jalan Karimata 49, Jember, 68121, Indonesia.

Department of Chemical Engineering, Faculty of Engineering, Universitas Jember, Jalan Kalimantan 37, Jember, 68121, Indonesia.

出版信息

Heliyon. 2023 Oct 22;9(11):e21350. doi: 10.1016/j.heliyon.2023.e21350. eCollection 2023 Nov.

Abstract

Membrane bioreactor (MBR) deteriorates due to fouling on the membrane pores, which can reduce the membrane performance. To reduce membrane fouling, the addition of inorganic filler can enhance the antifouling properties. This study investigates two different membrane preparation by thermally induced phase separation (TIPS) and dip coating methods to modify hollow fiber membrane with Silver Nanoparticles (AgNPs)-Zeolites used in MBR for industrial wastewater treatment. Performance was evaluated by analyzing the flux of water and wastewater, rejection, water content, and antifouling properties. Characterization result represented the synthesized silver nanoparticles had similar diffraction peak with commercial AgNPs, then the micrograph of AgNPs and zeolites addition membrane showed that the inorganic material had an octahedral shape representing zeolite crystal and irregular shape representing AgNPs. The addition of zeolites and AgNPs resulted in satisfying performance, increased flux, rejection, and antifouling properties.

摘要

膜生物反应器(MBR)会因膜孔污染而性能下降,这会降低膜的性能。为减少膜污染,添加无机填料可增强抗污染性能。本研究通过热致相分离(TIPS)和浸涂法研究了两种不同的膜制备方法,用银纳米颗粒(AgNPs)-沸石对用于工业废水处理的中空纤维膜进行改性。通过分析水和废水的通量、截留率、含水量和抗污染性能来评估性能。表征结果表明,合成的银纳米颗粒与商业AgNPs具有相似的衍射峰,添加AgNPs和沸石的膜的显微照片显示,无机材料具有代表沸石晶体的八面体形状和代表AgNPs的不规则形状。沸石和AgNPs的添加带来了令人满意的性能,通量、截留率和抗污染性能均有所提高。

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