Reductions of multiple air pollutants from coking industry through technology improvements and their impacts on air quality and health risks in a highly industrialized region of China.

The Beijing-Tianjin-Hebei (BTH) region, a highly industrialized area in China, boasts a concentration of coking plants that constitute a vital component of the steel industry. In recent years, the Chinese government has implemented measures including backward production capacity elimination (BPCE), ultra-low emission technology transformation (ULET), and deep treatment of volatile organic compounds (DTV), to promote technological progress in the coking industry and mitigate the impact of pollutant emissions. This study focuses on the emission trends, reduction effects of various measures, and the impact on air quality and human health in the regional scale. The findings reveal that in 2015, the emissions of PM, SO, NOx and VOCs of the coking industry in BTH region were 29.15, 9.64, 26.62 and 82.99 Gg (1000 tons/year) respectively. However, by 2019, these emissions had significantly decreased by 19.95, 5.78, 18.69, and 22.53 Gg, respectively. Of these reductions, ULET contributed about 80.3 % of NOx and SO, and 57.4 % of PM. Meanwhile, DTV and BPCE contributed 49.2 % and 50.7 % of VOCs emission reduction, respectively. Despite the improvement effect on PM, SO, and NO is limited, the substantial decrease in VOCs (particularly benzene) resulted in a significant reduction in the coking industry's contribution to the atmospheric benzene concentration, dropping from 15.9 % in 2015 to 11.6 % in 2019. Moreover, the lifetime cancer risk (LCR) contribution of benzene inhalation in the BTH region also decreased from 1.7 × 10 to 1.2 × 10. Looking ahead to 2025, the continued implementation of DTV will be expected to reduce VOCs emissions by 24.41Gg. This will bring the industry's contribution to the benzene concentration down to 6.8 % and the cancer risk of the population to an acceptable level (LCR < 1 × 10). Additionally, the deep treatment of VOCs in coking plants will significantly reduce the health risks faced by people living in the vicinity of the plants.