1,3-亚苯基桥连的环状六萘与富勒烯C和C在溶液中的络合研究以及晶体中富勒烯的一维排列。
Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C and C in solution and 1D-alignment of fullerenes in the crystals.
作者信息
Mei Peifeng, Morimoto Hirofumi, Okada Yuta, Matsuo Kyohei, Hayashi Hironobu, Saeki Akinori, Yamada Hiroko, Aratani Naoki
机构信息
Division of Materials Science, Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma 630-0192 Japan
Department of Applied Chemistry, Graduate School of Engineering, Osaka University 2-1 Yamadaoka Suita 565-0871 Japan.
出版信息
RSC Adv. 2023 Nov 14;13(47):33459-33462. doi: 10.1039/d3ra06526j. eCollection 2023 Nov 7.
To investigate the host ability of a simple macrocycle, 1,3-phenylene-bridged naphthalene hexamer N6, we evaluated the complexation of N6 with fullerenes in toluene and in the crystals. The complexes in the solid-state demonstrate the one-dimensional alignment of fullerenes. The single-crystals of the C@N6 composite have semiconductive properties revealed by photoconductivity measurements.
为了研究简单大环化合物1,3-亚苯基桥连萘六聚体N6的主体能力，我们评估了N6与富勒烯在甲苯溶液中和晶体中的络合情况。固态络合物显示出富勒烯的一维排列。通过光电导率测量发现，C@N6复合材料的单晶具有半导体性质。
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