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集成过渡金属二硫属化物(TMDs)和MXenes的分子印迹聚合物基传感器综述

Molecularly Imprinted Polymer-Based Sensors Integrated with Transition Metal Dichalcogenides (TMDs) and MXenes: A Review.

作者信息

Thotathil Vandana, Sidiq Naheed, Al Marri Jawaher S, Zaidi Shabi Abbas

机构信息

Department of Chemistry and Earth Sciences, College of Arts and Sciences, Qatar University, Doha, Qatar.

出版信息

Crit Rev Anal Chem. 2025;55(3):516-541. doi: 10.1080/10408347.2023.2298339. Epub 2023 Dec 28.

Abstract

Molecularly imprinted polymer (MIP)-based electrochemical sensors have been extensively researched due to their higher sensitivity, quick response, and operational ease. To develop more advanced sensing devices with enhanced properties, MIPs have been integrated with two-dimensional (2D) layered materials such as transition metal dichalcogenides (TMDs) and MXenes. These 2D materials have unique electronic properties and an extended surface area, making them promising sensing materials that can improve the performance of MIPs. In this review article, we describe the methods used for the synthesis of TMDs and MXenes integrated MIP-based electrochemical sensors. Furthermore, we have provided a critical review of a wide range of analytes determined through the application of these electrochemical sensors. We also go over the influence of TMDs and MXenes on the binding kinetics and adsorption capacity which has enhanced binding recognition and sensing abilities. The combination of TMDs and MXenes with MIPs shows promising synergy in the development of highly efficient recognition materials. In the future, these sensors could be explored for a wider range of applications in environmental remediation, drug delivery, energy storage, and more. Finally, we address the challenges and future perspectives of using TMDs and MXenes integrated MIPs. We conclude with a focus on future development and the scope of integrating these materials in sensing technology.

摘要

基于分子印迹聚合物(MIP)的电化学传感器因其更高的灵敏度、快速响应和操作简便性而得到了广泛研究。为了开发具有更优异性能的先进传感装置,MIP已与二维(2D)层状材料(如过渡金属二硫属化物(TMD)和MXene)集成。这些二维材料具有独特的电子特性和较大的表面积,使其成为有望改善MIP性能的传感材料。在这篇综述文章中,我们描述了用于合成TMD和MXene集成的基于MIP的电化学传感器的方法。此外,我们对通过应用这些电化学传感器测定的多种分析物进行了批判性综述。我们还探讨了TMD和MXene对结合动力学和吸附容量的影响,这增强了结合识别和传感能力。TMD和MXene与MIP的结合在高效识别材料的开发中显示出有前景的协同作用。未来,这些传感器可在环境修复、药物递送、能量存储等更广泛的应用中进行探索。最后,我们阐述了使用TMD和MXene集成MIP的挑战和未来展望。我们以关注未来发展以及将这些材料集成到传感技术中的范围作为结论。

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