Quantitative Study on the Influence of Bromide Ions toward the Reduction Kinetics for Size-Tunable Palladium Nanocubes.

During the preparation of nanocrystals, regulating the dosage of key additives in the reaction system and the reaction temperature commonly affects the sizes and morphologies of the products. Despite the fact that bromide ions play a pivotal role in the synthesis of palladium nanocubes (Pd NCs), there is still a lack of quantitative and in-depth research on how the ions affect the reduction kinetics of Pd precursors and further on products. In this work, Pd NCs with different sizes have been prepared under various reaction conditions coupled to a systematic mechanism study. Quantitative measurements demonstrate that the reduction processes could be considered quasi-first-order reactions, and the corresponding kinetic parameters have been obtained. Furthermore, a linear relationship is discovered between and the average size () of Pd NCs. The investigation on the growth patterns of four chosen systems reveals that given reaction conditions lead to certain results with unique growth patterns.