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粉煤灰含量对干湿硫酸盐侵蚀作用下砂浆试件耐久性的影响

Influence of Fly Ash Content on the Durability of Mortar Specimens under Dry/Wet Sulfate Attack.

作者信息

Zhang Yage, Wu Dongge, Wang Yushan, Zhou Yang, Wang Shan, Zhao Yi

机构信息

College of Water Conservancy & Architectural Engineering, Shihezi University, Shihezi 832000, China.

Xinjiang Hongyuan Construction Group Co., Ltd., Cocodala 835219, China.

出版信息

Materials (Basel). 2023 Dec 25;17(1):113. doi: 10.3390/ma17010113.

Abstract

To investigate the durability of cementitious materials under complex environmental conditions in Xinjiang, this study conducted durability tests on mortar specimens with different fly ash contents under dry/wet sulfate attack conditions, with standard curing and steam curing at 70 °C. The appearance loss and flexural and compressive strength variations in the specimens were analyzed, and an evolution model of the mortar strength under a dry/wet sulfate attack was established. Moreover, XRD and SEM techniques were used to characterize the erosion products and microstructure, and to explore the erosion resistance mechanism of fly ash cementitious materials. The results showed that, after 160 cycles of erosion, the flexural strength of the specimens decreased with the increase in the fly ash content. In the context of steam-cured mortar specimens, throughout the entire erosion period, specimens with a fly ash content of 45% exhibited the highest relative compressive strength. The established strength evolution model had a minimum determination coefficient of 0.879, indicating a good agreement between the model and experimental results. Microscopic research showed that fly ash would undergo a pozzolanic reaction under the action of sulfate and calcium hydroxide, which was beneficial to the improvement of the erosion resistance. As the fly ash content increased, the erosion products of the specimens gradually became dominated by gypsum.

摘要

为研究新疆复杂环境条件下胶凝材料的耐久性,本研究对不同粉煤灰含量的砂浆试件在干湿硫酸盐侵蚀条件下进行耐久性试验,试件分别采用标准养护和70℃蒸汽养护。分析了试件的外观损失以及抗折和抗压强度变化情况,建立了干湿硫酸盐侵蚀作用下砂浆强度的演化模型。此外,采用XRD和SEM技术对侵蚀产物和微观结构进行表征,探讨粉煤灰胶凝材料的抗侵蚀机理。结果表明,经过160次侵蚀循环后,试件的抗折强度随粉煤灰含量的增加而降低。在蒸汽养护砂浆试件的情况下,在整个侵蚀期内,粉煤灰含量为45%的试件表现出最高的相对抗压强度。所建立的强度演化模型的决定系数最小值为0.879,表明模型与试验结果吻合良好。微观研究表明,粉煤灰在硫酸盐和氢氧化钙作用下会发生火山灰反应,这有利于提高抗侵蚀性。随着粉煤灰含量的增加,试件的侵蚀产物逐渐以石膏为主。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77a3/10780072/196de9c131b9/materials-17-00113-g001.jpg

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