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利用可见-近红外光谱法鉴别赤霞珠酿酒葡萄的成熟阶段

Discrimination of Maturity Stages of Cabernet Sauvignon Wine Grapes Using Visible-Near-Infrared Spectroscopy.

作者信息

Zhou Xuejian, Liu Wenzheng, Li Kai, Lu Dongqing, Su Yuan, Ju Yanlun, Fang Yulin, Yang Jihong

机构信息

College of Enology, Northwest A&F University, Yangling 712100, China.

College of Food Science and Pharmacy, Xinjiang Agricultural University, Urumqi 830052, China.

出版信息

Foods. 2023 Dec 4;12(23):4371. doi: 10.3390/foods12234371.

Abstract

Grape quality and ripeness play a crucial role in producing exceptional wines with high-value characteristics, which requires an effective assessment of grape ripeness. The primary purpose of this research is to explore the possible application of visible-near-infrared spectral (Vis-NIR) technology for classifying the maturity stages of wine grapes based on quality indicators. The reflection spectra of Cabernet Sauvignon grapes were recorded using a spectrometer in the spectral range of 400 nm to 1029 nm. After measuring the soluble solids content (SSC), total acids (TA), total phenols (TP), and tannins (TN), the grape samples were categorized into five maturity stages using a spectral clustering method. A traditional supervised classification method, a support vector machine (SVM), and two deep learning techniques, namely stacked autoencoders (SAE) and one-dimensional convolutional neural networks (1D-CNN), were employed to construct a discriminant model and investigate the association linking grape maturity stages and the spectral responses. The spectral data went through three commonly used preprocessing methods, and feature wavelengths were extracted using a competitive adaptive reweighting algorithm (CARS). The spectral data model preprocessed via multiplicative scattering correction (MSC) outperformed the other two preprocessing methods. After preprocessing, a comparison was made between the discriminant models established with full and effective spectral data. It was observed that the SAE model, utilizing the feature spectrum, demonstrated superior overall performance. The classification accuracies of the calibration and prediction sets were 100% and 94%, respectively. This study showcased the dependability of combining Vis-NIR spectroscopy with deep learning methods for rapidly and accurately distinguishing the ripeness stage of grapes. It has significant implications for future applications in wine production and the development of optoelectronic instruments tailored to the specific needs of the winemaking industry.

摘要

葡萄的品质和成熟度对于生产具有高价值特性的优质葡萄酒起着至关重要的作用,这需要对葡萄成熟度进行有效的评估。本研究的主要目的是探索可见 - 近红外光谱(Vis - NIR)技术基于品质指标对酿酒葡萄成熟阶段进行分类的可能应用。使用光谱仪在400 nm至1029 nm的光谱范围内记录赤霞珠葡萄的反射光谱。在测量了可溶性固形物含量(SSC)、总酸(TA)、总酚(TP)和单宁(TN)之后,采用光谱聚类方法将葡萄样品分为五个成熟阶段。采用传统的监督分类方法、支持向量机(SVM)以及两种深度学习技术,即堆叠自编码器(SAE)和一维卷积神经网络(1D - CNN),构建判别模型并研究葡萄成熟阶段与光谱响应之间的关联。光谱数据经过三种常用的预处理方法,并使用竞争性自适应重加权算法(CARS)提取特征波长。通过乘法散射校正(MSC)预处理的光谱数据模型优于其他两种预处理方法。预处理后,对使用完整和有效光谱数据建立的判别模型进行了比较。观察到利用特征光谱的SAE模型表现出卓越的整体性能。校准集和预测集的分类准确率分别为100%和94%。本研究展示了将Vis - NIR光谱与深度学习方法相结合用于快速准确区分葡萄成熟阶段的可靠性。它对未来在葡萄酒生产中的应用以及为酿酒行业特定需求定制的光电仪器的开发具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca11/10706061/2ea5d0d10f38/foods-12-04371-g001.jpg

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