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镜上纳米颗粒纳米腔的构建及其在等离子体增强光谱学中的应用。

Construction of nanoparticle-on-mirror nanocavities and their applications in plasmon-enhanced spectroscopy.

作者信息

Peng Wei, Zhou Jing-Wen, Li Mu-Lin, Sun Lan, Zhang Yue-Jiao, Li Jian-Feng

机构信息

College of Energy, State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, College of Chemistry and Chemical Engineering, Xiamen University Xiamen 361005 China

College of Chemistry, Chemical Engineering and Environment, Minnan Normal University Zhangzhou 363000 China.

出版信息

Chem Sci. 2024 Jan 16;15(8):2697-2711. doi: 10.1039/d3sc05722d. eCollection 2024 Feb 22.

DOI:10.1039/d3sc05722d
PMID:38404398
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10882497/
Abstract

Plasmonic nanocavities exhibit exceptional capabilities in visualizing the internal structure of a single molecule at sub-nanometer resolution. Among these, an easily manufacturable nanoparticle-on-mirror (NPoM) nanocavity is a successful and powerful platform for demonstrating various optical phenomena. Exciting advances in surface-enhanced spectroscopy using NPoM nanocavities have been developed and explored, including enhanced Raman, fluorescence, phosphorescence, upconversion, This perspective emphasizes the construction of NPoM nanocavities and their applications in achieving higher enhancement capabilities or spatial resolution in dark-field scattering spectroscopy and plasmon-enhanced spectroscopy. We describe a systematic framework that elucidates how to meet the requirements for studying light-matter interactions through the creation of well-designed NPoM nanocavities. Additionally, it provides an outlook on the challenges, future development directions, and practical applications in the field of plasmon-enhanced spectroscopy.

摘要

等离子体纳米腔在以亚纳米分辨率可视化单个分子的内部结构方面展现出卓越能力。其中，易于制造的镜上纳米颗粒（NPoM）纳米腔是展示各种光学现象的成功且强大的平台。利用NPoM纳米腔的表面增强光谱学已取得令人兴奋的进展并得到探索，包括增强拉曼、荧光、磷光、上转换等。本观点强调了NPoM纳米腔的构建及其在暗场散射光谱学和等离子体增强光谱学中实现更高增强能力或空间分辨率方面的应用。我们描述了一个系统框架，阐明了如何通过创建精心设计的NPoM纳米腔来满足研究光与物质相互作用的要求。此外，它还展望了等离子体增强光谱学领域的挑战、未来发展方向及实际应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/76f5982340e5/d3sc05722d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/814e3def3625/d3sc05722d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/ab619a664527/d3sc05722d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/747c313349e1/d3sc05722d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/a360b1a63e36/d3sc05722d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/6cf389e8cd38/d3sc05722d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/76f5982340e5/d3sc05722d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/814e3def3625/d3sc05722d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/ab619a664527/d3sc05722d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/747c313349e1/d3sc05722d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/a360b1a63e36/d3sc05722d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/6cf389e8cd38/d3sc05722d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b4f/10882497/76f5982340e5/d3sc05722d-f6.jpg

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