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二维纳米层状 MXene 在分析和修复水中内分泌干扰化合物和重金属方面的潜在应用。

Potential application of 2D nano-layered MXene in analysing and remediating endocrine disruptor compounds and heavy metals in water.

机构信息

Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia.

Department of Chemical Engineering and Materials Science, Yuan Ze University, Taoyuan, Taiwan.

出版信息

Environ Geochem Health. 2024 Mar 11;46(3):111. doi: 10.1007/s10653-024-01917-4.

Abstract

With the advancement of technologies and growth of the economy, it is inevitable that more complex processes are deployed, producing more heterogeneous wastewater that comes from biomedical, biochemical and various biotechnological industries. While the conventional way of wastewater treatment could effectively reduce the chemical oxygen demand, pH and turbidity of wastewater, trace pollutants, specifically the endocrine disruptor compounds (EDCs) that exist in µg L or ng L have further hardened the detection and removal of these biochemical pollutants. Even in small amounts, EDC could interfere human's hormone, causing severe implications on human body. Hence, this review elucidates the recent insights regarding the effectiveness of an advanced 2D material based on titanium carbide (TiCT), also known as MXene, in detecting and removing EDCs. MXene's highly tunable feature also allows its surface chemistry to be adjusted by adding chemicals with different functional groups to adsorb different kinds of EDCs for biochemical pollution mitigation. At the same time, the incorporation of MXene into sample matrices also further eases the analysis of trace pollutants down to ng L levels, thereby making way for a more cleaner and comprehensive wastewater treatment. In that sense, this review also highlights the progress in synthesizing MXene from the conventional method to the more modern approaches, together with their respective key parameters. To further understand and attest to the efficacy of MXene, the limitations and current gaps of this potential agent are also accentuated, targeting to seek resolutions for a more sustainable application.

摘要

随着技术的进步和经济的增长,越来越复杂的工艺被采用是不可避免的,这会产生更多来自生物医学、生化和各种生物技术产业的异质废水。虽然传统的废水处理方法可以有效地降低废水的化学需氧量、pH 值和浊度,但痕量污染物,特别是以微克/升或纳克/升存在的内分泌干扰化合物(EDCs),进一步增加了这些生化污染物的检测和去除难度。即使在少量存在的情况下,EDC 也可能干扰人类的激素,对人体造成严重影响。因此,本文综述了最近关于基于碳化钛(TiCT)的二维材料(也称为 MXene)在检测和去除 EDCs 方面的有效性的研究进展。MXene 具有高度可调的特性,允许通过添加具有不同官能团的化学物质来调整其表面化学,以吸附不同种类的 EDCs,从而减轻生化污染。同时,将 MXene 纳入样品基质中也进一步简化了痕量污染物低至 ng L 水平的分析,从而为更清洁、更全面的废水处理铺平了道路。从这个意义上说,本文还强调了从传统方法到更现代方法合成 MXene 的进展,以及它们各自的关键参数。为了进一步理解和证明 MXene 的功效,还强调了这种潜在试剂的局限性和当前差距,旨在寻求更可持续应用的解决方案。

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