Chen Yongliang, Li Anmin, Jiang Shiwei
School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.
State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China.
Materials (Basel). 2024 Feb 28;17(5):1095. doi: 10.3390/ma17051095.
In 2023, the global production of new red mud is expected to reach nearly 200 million tons, but less than 10% of it is currently being utilized in an environmentally friendly manner. To reduce the sintering temperature of alumina ceramics, a sintering aid method is used, as high-purity alumina ceramics require a solid-phase sintering temperature of over 1700 °C. The metal oxides present in red mud are necessary components for high-performance composite alumina ceramics. Composites were obtained by mixing and sintering red mud and AlO. This study focused on the mechanical properties and wettability of these composites. The results indicated that the 10% red mud-AlO composite exhibited the highest hardness (20.12 GPa) and flexural strength (346 MPa). This is attributed to the formation of a mineral phase dominated by CaAlO, generated by the red mud during the sintering process, which filled the pores and reduced porosity. The surface energy of the red mud-AlO composite was the highest at room temperature and high temperature, reaching 49.60 mJ·m-2 and 1164.7 mJ·m-2, respectively, indicating that it has better stability at both room and high temperatures. This study provides an important fundamental basis for the application of red mud-alumina composites to replace alumina-based composites in the field of construction materials, molten metal filters, ceramic cleavers, etc.
2023年,全球新产生的赤泥产量预计将达到近2亿吨,但目前以环保方式利用的赤泥不到10%。为降低氧化铝陶瓷的烧结温度,采用了烧结助剂法,因为高纯度氧化铝陶瓷需要超过1700℃的固相烧结温度。赤泥中存在的金属氧化物是高性能复合氧化铝陶瓷的必要成分。通过将赤泥和AlO混合并烧结获得了复合材料。本研究重点关注这些复合材料的力学性能和润湿性。结果表明,10%的赤泥-AlO复合材料表现出最高的硬度(20.12 GPa)和抗弯强度(346 MPa)。这归因于在烧结过程中赤泥生成的以CaAlO为主的矿相的形成,该矿相填充了孔隙并降低了孔隙率。赤泥-AlO复合材料在室温及高温下的表面能最高,分别达到49.60 mJ·m-2和1164.7 mJ·m-2,表明其在室温和高温下均具有较好的稳定性。本研究为赤泥-氧化铝复合材料在建筑材料、熔融金属过滤器、陶瓷切割器等领域替代氧化铝基复合材料的应用提供了重要的基础依据。