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采用电子传感器和热解吸-气相色谱-质谱联用技术对室内建筑材料 VOCs 排放源的研究。

Investigation on the source of VOCs emission from indoor construction materials using electronic sensors and TD-GC-MS.

机构信息

Department of Chemistry, University of Cyprus, P.O. Box 20537, Nicosia, 1678, Cyprus.

Laboratory of Chemical Engineering and Engineering Sustainability, Faculty of Pure and Applied Sciences, Open University of Cyprus, Giannou Kranidioti 89, Nicosia, 2231, Cyprus.

出版信息

Environ Pollut. 2024 May 1;348:123765. doi: 10.1016/j.envpol.2024.123765. Epub 2024 Mar 17.

Abstract

Indoor air quality (IAQ) is critical to the health and wellbeing of people. As the majority of people spend greater amounts of time indoors, either in office spaces or households, the level of air pollutants in such environments is critical. Building materials and furniture are known sources of air pollutants such as Volatile Organic Compounds (VOCs) and may be associated with discomfort, detrimental health of the occupants, etc. In this study, the VOCs found in a brand new office complex were monitored over a period of 6 months, with an emphasis on monitoring and quantifying harmful VOCs and identifying their emission source. Air samples were taken from a closed, unoccupied office space on a weekly basis and analysed using Thermal Desorption-Gas Chromatography-Mass Spectrometry (TD-GC-MS), while continuous monitoring of the air quality was performed using two commercially available IAQ sensors. To identify the source of the emitted VOCs, pieces of all construction material that were used in the office, including flooring, finished wall material, and adhesive glues, were removed, and placed in air-tight glass containers prior to analysis confirming that the source of VOCs is indeed the flooring. Identified compounds included mainly material origin VOCs such as BTEX (benzene, toluene, ethylbenzene, xylene) and styrene, but also common VOCs such as acetone and propan-2-ol. Of significant importance was the concentration of toluene that was found to be the most abundant VOC in both the flooring material and the indoor air.

摘要

室内空气质量 (IAQ) 对人们的健康和福祉至关重要。由于大多数人在室内花费更多的时间,无论是在办公空间还是家庭中,因此这些环境中的空气污染物水平至关重要。建筑材料和家具是空气污染物的已知来源,例如挥发性有机化合物 (VOC),并且可能与不适、居住者健康受损等有关。在这项研究中,监测了一个全新的办公大楼内的 VOCs,为期 6 个月,重点监测和量化有害 VOC 并确定其排放源。每周从一个封闭、无人占用的办公空间中采集空气样本,并使用热解吸-气相色谱-质谱联用仪 (TD-GC-MS) 进行分析,同时使用两个市售的室内空气质量传感器进行连续监测。为了确定排放 VOC 的来源,从办公室使用的所有建筑材料(包括地板、已完成的墙壁材料和胶黏剂)上取下小块材料,并在进行分析之前将其放入密封的玻璃容器中,从而确认 VOC 的来源确实是地板。鉴定出的化合物主要包括材料来源 VOC,如苯、甲苯、乙苯、二甲苯和苯乙烯,但也包括常见的 VOC,如丙酮和异丙醇。甲苯的浓度非常重要,它被发现是地板材料和室内空气中含量最丰富的 VOC。

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