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镧系掺杂上转换纳米材料的多功能光学传感:提高可见光和近红外范围内温度和压力的检测性能

Multifunctional Optical Sensing with Lanthanide-Doped Upconverting Nanomaterials: Improving Detection Performance of Temperature and Pressure in the Visible and NIR Ranges.

作者信息

Saidi Kamel, Yangui Mariem, Hernández-Álvarez Christian, Dammak Mohamed, Rafael Martín Benenzuela Inocencio, Runowski Marcin

机构信息

Laboratoire de Physique Appliquée, Groupe des Matériaux Luminescents, Faculté des Sciences de Sfax, Département de Physique, Université de Sfax, BP 1171 Sfax, Tunisia.

Departamento de Física, MALTA-Consolider Team, IMN and IUdEA, Universidad de La Laguna, Apdo. Correos 456, E-38206 San Cristóbal de La Laguna, Santa Cruz de Tenerife, Spain.

出版信息

ACS Appl Mater Interfaces. 2024 Apr 17;16(15):19137-19149. doi: 10.1021/acsami.4c00313. Epub 2024 Apr 6.

Abstract

Temperature and pressure are fundamental physical parameters in the field of materials science, making their monitoring of utmost significance for scientists and engineers. Here, the NaSrY(MoO4):0.02Er/0.01Tm/0.15Yb nanophosphor is developed as an optical sensor material. Under 975 nm laser excitation, the upconversion characteristics and optical detection performance of the multifunctional sensing platform of temperature and pressure (vacuum) are investigated. We have successfully developed a novel detection platform that enables optical detection of pressure (vacuum) and temperature. This platform utilizes thermally coupled levels (TCLs) and non-TCLs of Er and Tm to achieve ratiometric detection. The multimodal optical temperature and pressure detection based on TCLs and non-TCLs is successfully realized by using different emission bands of double emission centers, which makes it possible for self-referencing optical temperature and pressure measurement modes. These results indicate that the developed nanophosphor is a promising candidate for optical sensors, and our findings suggest potential strategies for modulating the sensor properties of luminescent materials doped with rare-earth ions.

摘要

温度和压力是材料科学领域的基本物理参数,因此对其进行监测对科学家和工程师而言至关重要。在此,开发了NaSrY(MoO4):0.02Er/0.01Tm/0.15Yb纳米磷光体作为一种光学传感材料。在975 nm激光激发下,研究了温度和压力(真空)多功能传感平台的上转换特性和光学检测性能。我们成功开发了一种新型检测平台,可实现对压力(真空)和温度的光学检测。该平台利用Er和Tm的热耦合能级(TCLs)和非热耦合能级来实现比率检测。通过使用双发射中心的不同发射带,成功实现了基于TCLs和非TCLs的多模态光学温度和压力检测,这使得自参考光学温度和压力测量模式成为可能。这些结果表明,所开发的纳米磷光体是一种很有前景的光学传感器候选材料,我们的研究结果为调制掺杂稀土离子的发光材料的传感器性能提供了潜在策略。

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