Eco-Friendly, Biodegradable Starch-Based Packaging Materials with Antioxidant Features.

Due to the extensive application of petroleum-based plastics as packaging materials and problems related to their degradation/recycling, developing new solutions in the field of novel biopolymer-based materials has become imperative. Natural substitutes for synthetic polymers (starch, cellulose, chitosan) require modifications that enable their processing and provide them with additional properties (i.e., mechanical strength, controlled biodeterioration, antimicrobial and antioxidative activity). The antioxidant activity of natural packaging materials still requires further investigation. In this research paper, novel materials used for packaging perishable food susceptible to oxidizing agents were designed from potato starch (NS) reinforced with antioxidants such as dialdehyde starch (DS) and caffeic acid (CA)/quinic acid (QA). The use of spectroscopic techniques (ATR-FTIR, Raman) and X-ray diffraction allowed the examination of the chemical structure and arrangement of the blend and confirmed the component interactions. The film surface was examined by AFM. DS, functioning as a cross-linker, enhanced the film barrier as well as the mechanical and thermal properties, and it promoted starch amorphization when blended with other antioxidants. The antioxidant activity of caffeic acid was greater than that of quinic acid. Dialdehyde starch improves elasticity, whereas acids (particularly caffeic acid) influence film stiffness. A high susceptibility to biodegradation is valuable for potential eco-friendly packaging applications.